115460
氟代丙酮
98%
别名:
α-Fluoroacetone, 1-Fluoro-2-propanone, Fluoromethyl methyl ketone, Monofluoroacetone
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关于此项目
线性分子式:
CH3COCH2F
化学文摘社编号:
分子量:
76.07
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
207-064-0
MDL number:
Assay:
98%
Quality Level
assay
98%
refractive index
n20/D 1.37 (lit.)
bp
75 °C (lit.)
density
1.054 g/mL at 25 °C (lit.)
functional group
fluoro, ketone
storage temp.
2-8°C
SMILES string
CC(=O)CF
InChI
1S/C3H5FO/c1-3(5)2-4/h2H2,1H3
InChI key
MSWVMWGCNZQPIA-UHFFFAOYSA-N
General description
Aldolizations of fluoroacetone with aldehydes mediated by organocatalyst yield products with high enantioselectivities.
Application
Fluoroacetone has been used as a catalyst to study the kinetics of the ketone-catalysed decomposition of peroxymonosulfuric acid (Caro′s acid).
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 2 Dermal - Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Flam. Liq. 2
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
44.6 °F - closed cup
flash_point_c
7 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Y Shiratori et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 56A(9), 1693-1701 (2000-08-22)
The effects of water and heavy water on conformational equilibria of fluoroacetone have been investigated via Raman spectroscopy. Additional Raman bands have been observed in the C-F stretching and the C-C-C symmetric stretching regions for the aqueous solutions. Based on
Lange A, et al.
J. Chem. Soc. Perkin Trans. II, 7, 1343-1350 (1999)
Kimiyasu Isobe et al.
Applied microbiology and biotechnology, 102(3), 1307-1316 (2017-12-15)
The enzyme responsible for the enantioselective production of (S)-1,1,1-trifluoro-2-propanol ((S)-TFP) from 1,1,1-trifluoroacetone (TFA) has been identified in Ogataea polymorpha NBRC 0799. We purified two carbonyl reductases, OpCRD-A and OpCRD-B from this strain, and revealed their characteristics. Both enzymes were specific
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 115460-1G | 04061836690977 |
| 115460-5G | 04061836681982 |