15420
N-(叔丁氧羰基)甘氨酰胺
≥99.0% (T), for peptide synthesis
别名:
N-(叔丁氧羰基)甘氨酸, BOC-甘氨酸
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关于此项目
线性分子式:
(CH3)3COCONHCH2COOH
化学文摘社编号:
分子量:
175.18
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352209
EC Number:
224-864-5
MDL number:
Beilstein/REAXYS Number:
1101514
产品名称
N-(叔丁氧羰基)甘氨酰胺, ≥99.0% (T)
InChI key
VRPJIFMKZZEXLR-UHFFFAOYSA-N
InChI
1S/C7H13NO4/c1-7(2,3)12-6(11)8-4-5(9)10/h4H2,1-3H3,(H,8,11)(H,9,10)
SMILES string
CC(C)(C)OC(=O)NCC(O)=O
assay
≥99.0% (T)
form
powder or crystals
reaction suitability
reaction type: Boc solid-phase peptide synthesis
ign. residue
≤0.05%
Quality Level
application(s)
peptide synthesis
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Application
Boc-Gly-OH可用于：
- 肽化学中通过酯化反应合成N-Boc氨基酸酯。
- 合成三肽H-Gly-Pro-Glu-OH，其是一种神经保护药的类似物。
- 作为腙和靛蓝烯丙基化的促进剂。
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Faceshields, Gloves
Analogues of the neuroprotective tripeptide Gly-Pro-Glu (GPE): synthesis and structure-activity relationships.
De Diego SAA, et al.
Bioorganic & Medicinal Chemistry Letters, 15(9), 2279-2283 (2005)
Ceric ammonium nitrate (CAN) mediated esterification of N-Boc amino acids allows either retention or removal of the N-Boc group.
Kuttan A, et al.
Tetrahedron Letters, 45(12), 2663-2665 (2004)
Wen-Ren Li et al.
The Journal of organic chemistry, 67(14), 4702-4706 (2002-07-06)
A new approach to a CD45 protein tyrosine phosphatase inhibitor, pulchellalactam, is described. The key step of the sequence involves addition and elimination of an enolic lactam in a single step and 70% yield, employing an organocuprate reagent. The resulting
N-Boc-glycine-assisted indium-mediated allylation reaction: a sustainable approach.
Vemula SR, et al.
Tetrahedron Letters, 56(23), 3322-3325 (2015)
Alexey Krushelnitsky et al.
Journal of magnetic resonance (San Diego, Calif. : 1997), 182(2), 339-342 (2006-07-21)
As demonstrated by means of the one-dimensional solid-state MAS exchange experiment (CODEX), the rate of the proton driven spin diffusion between backbone (15)N nuclei in totally enriched protein depends strongly on the magic angle spinning (MAS) frequency: spin diffusion at
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