208353
五氯化钼
95%
别名:
Molybdenum pentachloride, Pentachloromolybdenum
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关于此项目
线性分子式:
MoCl5
化学文摘社编号:
分子量:
273.21
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352302
MDL number:
Assay:
95%
Form:
powder
Quality Level
vapor pressure
1.75 mmHg ( 25 °C), 131 mmHg ( 250 °C)
assay
95%
form
powder
reaction suitability
core: molybdenum, reagent type: catalyst
impurities
<0.5% insoluble matter
bp
268 °C (lit.)
mp
194 °C (lit.)
density
2.928 g/mL at 25 °C (lit.)
SMILES string
Cl[Mo](Cl)(Cl)(Cl)Cl
InChI
1S/5ClH.Mo/h5*1H;/q;;;;;+5/p-5
InChI key
GICWIDZXWJGTCI-UHFFFAOYSA-I
General description
氯化钼（V）是一种路易斯酸，被广泛用作许多有机反应的催化剂和试剂。它可以由钼金属的直接氯化或亚硫酰氯和 MoO3的加热回流制备。
Application
氯化钼（V）可用作以下反应的高效催化剂：
它也可用作合成氧化铝/钼纳米复合材料和亚甲基钼试剂的前体，用于化学选择性羰基烯化反应。
- 硝基苯和醇的缩合以及烯基锂试剂的C-C偶联。
- 苄基醇与磺胺和氨基甲酸酯的直接酰胺化反应。
它也可用作合成氧化铝/钼纳米复合材料和亚甲基钼试剂的前体，用于化学选择性羰基烯化反应。
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signalword
Danger
hcodes
Hazard Classifications
Carc. 2 - Eye Dam. 1 - Skin Corr. 1B
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
法规信息
危险化学品
此项目有
Kristina Hackeloer et al.
Organic letters, 13(5), 916-919 (2011-02-02)
A domino sequence involving various MoCl(5)-mediated oxidations followed by trapping and supposed [3,3]-sigmatropic rearrangement provides a fast access to the full carbon skeleton of metasequirin-B. A variety of different moieties R(1) and R(2) are tolerated.
Mladen Litvić et al.
Bioorganic & medicinal chemistry letters, 22(11), 3676-3681 (2012-05-02)
Mo(VI) and Mo(V) salts both react selectively with Hantzsch esters to produce substitute pyridines in good-to-excellent yield (75-99%). The remarkable reactivity and selectivity of MoOCl(4) under reflux of acetonitrile and MoCl(5) in dichloromethane at room temperature encouraged us to propose
Kumar, S. Manickam, M.
Chemical Communications (Cambridge, England), 1615-1615 (1997)
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 208353-25G | 04061838769718 |
| 208353-100G | 04061838769701 |