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Merck
CN

223689

二(氰基苯)二氯化钯(II)

greener alternative

95%, powder

别名:

二(氰基苯)二氯化钯(II), 二氯化钯双（苯甲腈）, 二氯双（苯甲腈）钯, 二氯双（苯甲腈）钯 (II), 二苯甲腈二氯化钯, 双（苯甲腈）二氯化钯 (II), 双（苯腈）二氯化钯, 氯化钯(II)双(苄腈)络合物, 苯甲腈钯络合物

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关于此项目

线性分子式:
(C6H5CN)2PdCl2
化学文摘社编号:
14220-64-5
分子量:
383.57
NACRES:
NA.22
PubChem Substance ID:
24853396
UNSPSC Code:
12161600
EC Number:
238-085-3
MDL number:
MFCD00013123
Beilstein/REAXYS Number:
3981730

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产品名称

二(氰基苯)二氯化钯(II), 95%

InChI key

WXNOJTUTEXAZLD-UHFFFAOYSA-L

InChI

1S/2C7H5N.2ClH.Pd/c2*8-6-7-4-2-1-3-5-7;;;/h2*1-5H;2*1H;/q;;;;+2/p-2

SMILES string

Cl[Pd]Cl.N#Cc1ccccc1.N#Cc2ccccc2

assay

95%

form

powder

reaction suitability

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst

greener alternative product characteristics

Catalysis
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sustainability

Greener Alternative Product

mp

131 °C (lit.)

greener alternative category

Aligned,

Quality Level

100

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相关类别

Application

双（笨腈）氯化钯（II）可作为催化剂，用于：
  • 通过 Wacker 氧化，从末端烯烃更绿色环保地合成胺，然后转移氢化所得亚胺。
  • 交叉偶联反应 和 α-O-糖苷化。

末端烯烃的正式反马氏氢胺化反应

General description

二（苯腈）氯化钯（II）是一咱种配位化合物，在Suzuki交叉偶联反应中用作催化剂。


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存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
MKCW3273
MKCW0545
0000315504
0000315504
MKCV6486

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Brandon P Schuff et al.
Organic letters, 9(16), 3173-3176 (2007-07-10)
A novel method for palladium-catalyzed stereoselective formation of alpha-O-glycosides has been developed. This strategy relies on the palladium-biaryl phosphine catalyst-glycal donor complexation to control the anomeric selectivity. It does not depend on the nature of the protecting groups on the
Wei Shi et al.
Chemical communications (Cambridge, England), (23), 2342-2344 (2007-09-12)
A direct alkynylation of readily available alpha-halo esters and amides with high yields is described herein; a distinct switch from diyne formation to alkynylation products was attained under neutral conditions.
Catalysts of Suzuki Cross-Coupling Based on Functionalized Hyper-cross-linked Polystyrene: Influence of Precursor Nature
Nemygina N, et al.
Organic Process Research & Development, 20(8), 1453-1460 (2019)
Shih-Chieh Yeh et al.
Polymers, 11(12) (2019-12-11)
A crucial polymer intermediate, 4-[1-(4-hydroxyphenyl)cyclopentyl]-phenol (bisphenol CP), was developed from dicyclopentadiene (DCPD), a key byproduct of the C5 fraction in petrochemicals. On the basis of bisphenol CP, a diamine, 4,4'-((cyclopentane-1,1-diylbis(4,1-phenylene))bis(oxy))-dianiline (cyclopentyl diamine; CPDA) was subsequently obtained through a nucleophilic substitution
Synthesis, 803-803 (1992)

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