232548
3-乙氧基异丁烯醛
96%
别名:
3-乙氧基-2-甲基丙烯醛
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关于此项目
线性分子式:
C2H5OCH=C(CH3)CHO
化学文摘社编号:
分子量:
114.14
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
255-899-4
MDL number:
产品名称
3-乙氧基异丁烯醛, 96%
InChI key
KDOAHVPFGIYCEU-UHFFFAOYSA-N
InChI
1S/C6H10O2/c1-3-8-5-6(2)4-7/h4-5H,3H2,1-2H3
SMILES string
CCOC=C(C)C=O
assay
96%
form
liquid
refractive index
n20/D 1.4792 (lit.)
bp
78-81 °C/14 mmHg (lit.)
density
0.96 g/mL at 25 °C (lit.)
functional group
aldehyde
ether
storage temp.
2-8°C
Quality Level
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Application
3-Ethoxymethacrolein was used in the synthesis of:
- 5,10-dideaza-5,6,7,8-tetrahydrofolic acid (DDATHF)
- quinolines via modified Friedlander synthesis
- 3-[2-isopropyl-5-methylcyclohexyloxy-(1R, 2S, 5R)]-2-methyl-2E-propenal
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Flam. Liq. 3
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
95.9 °F - closed cup
flash_point_c
35.5 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Photooxygenation of chiral dienol ethers: asymmetric synthesis of alkoxydioxines.
Dussault PH, et al.
Tetrahedron, 55(38), 11437-11454 (1999)
Synthesis of quinolines via ortho-lithiated N-acylanilines. A modified Friedlaender synthesis.
Cho IS, et al.
The Journal of Organic Chemistry, 56(26), 7288-7291 (1991)
E C Taylor et al.
Investigational new drugs, 14(3), 281-285 (1996-01-01)
A new and extremely efficient synthesis of DDATHF from 4-vinylbenzoic acid and bromomalondialdehyde as precursors has been developed which proceeds in 48% overall yield.
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