232548
3-乙氧基异丁烯醛
96%
别名:
3-乙氧基-2-甲基丙烯醛
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关于此项目
线性分子式:
C2H5OCH=C(CH3)CHO
化学文摘社编号:
分子量:
114.14
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
质量水平
方案
96%
表单
liquid
折射率
n20/D 1.4792 (lit.)
沸点
78-81 °C/14 mmHg (lit.)
密度
0.96 g/mL at 25 °C (lit.)
官能团
aldehyde
ether
储存温度
2-8°C
SMILES字符串
CCOC=C(C)C=O
InChI
1S/C6H10O2/c1-3-8-5-6(2)4-7/h4-5H,3H2,1-2H3
InChI key
KDOAHVPFGIYCEU-UHFFFAOYSA-N
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应用
3-Ethoxymethacrolein was used in the synthesis of:
- 5,10-dideaza-5,6,7,8-tetrahydrofolic acid (DDATHF)
- quinolines via modified Friedlander synthesis
- 3-[2-isopropyl-5-methylcyclohexyloxy-(1R, 2S, 5R)]-2-methyl-2E-propenal
警示用语：
Warning
危险分类
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Flam. Liq. 3
储存分类代码
3 - Flammable liquids
WGK
WGK 3
闪点(°F)
95.9 °F - closed cup
闪点(°C)
35.5 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Synthesis of quinolines via ortho-lithiated N-acylanilines. A modified Friedlaender synthesis.
Cho IS, et al.
The Journal of Organic Chemistry, 56(26), 7288-7291 (1991)
Photooxygenation of chiral dienol ethers: asymmetric synthesis of alkoxydioxines.
Dussault PH, et al.
Tetrahedron, 55(38), 11437-11454 (1999)
E C Taylor et al.
Investigational new drugs, 14(3), 281-285 (1996-01-01)
A new and extremely efficient synthesis of DDATHF from 4-vinylbenzoic acid and bromomalondialdehyde as precursors has been developed which proceeds in 48% overall yield.
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