242306
氯甲酸烯丙酯
97%, for peptide synthesis
别名:
2-Propen-1-yl chloroformate, Allyloxycarbonyl chloride
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关于此项目
线性分子式:
ClCOOCH2CH=CH2
化学文摘社编号:
分子量:
120.53
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12190000
EC Number:
220-916-6
MDL number:
Beilstein/REAXYS Number:
773915
产品名称
氯甲酸烯丙酯, 97%
InChI key
CAEWJEXPFKNBQL-UHFFFAOYSA-N
InChI
1S/C4H5ClO2/c1-2-3-7-4(5)6/h2H,1,3H2
SMILES string
ClC(=O)OCC=C
vapor pressure
3.67 psi ( 20 °C)
assay
97%
form
liquid
refractive index
n20/D 1.422 (lit.)
bp
~27 °C/11 mmHg (lit.)
density
1.134 g/mL at 20 °C (lit.)
application(s)
peptide synthesis
storage temp.
−20°C
Quality Level
General description
氯甲酸烯丙酯是一种有机化合物，用于合成各种化合物，如烯丙基氨基甲酸酯和烯丙基碳酸酯。此外，它可用于制备α-烯丙基羰基和α, β-不饱和羰基。
Application
氯甲酸烯丙酯可用于合成：
- 组蛋白及其类似物。
- 由环硫酯(d,l-高半胱氨酸 硫内脂盐酸盐)生成Alloc-TL单体 (N-(烯丙氧基)羰基高半胱氨酸硫代内酯) 。
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 1 Inhalation - Acute Tox. 3 Oral - Flam. Liq. 3 - Skin Corr. 1B
存储类别
3 - Flammable liquids
flash_point_f
87.8 °F - closed cup
flash_point_c
31 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
Allyl Chloroformate
Herrinton PM
Encyclopedia of Reagents for Organic Synthesis, Second Edition (2001)
Carlos E Cuevas-Suárez et al.
Journal of the mechanical behavior of biomedical materials, 87, 148-154 (2018-08-03)
Over the past years, significant effort has been dedicated to synthesizing low-shrinking formulations, however, development of dental composites with low volumetric shrinkage continues to be challenging. The purpose of this study was to synthesize a bisphenol allylic derivate (BPhADAC) and
Palladium-catalyzed synthesis of substituted cycloheptane-1,4-diones by an asymmetric ring-expanding allylation (AREA).
Sabrina R Schulz et al.
Angewandte Chemie (International ed. in English), 46(21), 3966-3970 (2007-04-20)
Thiolactone-based polymers for formaldehyde scavenging coatings
Resetco C, et al.
European Polymer Journal, 82, 166-174 (2016)
[Toxic action of allylchloroformate].
E F Oskerko et al.
Gigiena truda i professional'nye zabolevaniia, (5)(5), 51-52 (1984-05-01)
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