250090
1-氟辛烷
98%
别名:
辛基氟
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关于此项目
线性分子式:
CH3(CH2)7F
化学文摘社编号:
分子量:
132.22
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
207-333-2
MDL number:
Assay:
98%
Form:
liquid
产品名称
1-氟辛烷, 98%
InChI key
DHIVLKMGKIZOHF-UHFFFAOYSA-N
InChI
1S/C8H17F/c1-2-3-4-5-6-7-8-9/h2-8H2,1H3
SMILES string
CCCCCCCCF
assay
98%
form
liquid
refractive index
n20/D 1.396 (lit.)
bp
142-146 °C (lit.)
density
0.814 g/mL at 25 °C (lit.)
functional group
alkyl halide
fluoro
Quality Level
Application
1-Fluorooctane has been used as a molecular probe in evaluations of gas chromatographic stationary phases consisting of bromo- and chloro-derivatives of a C78 branched alkane.
General description
1-Fluorooctane undergoes C-F bond-cleavage reaction with phenyl magnesium chloride to give n-octylbenzene. It reacts rapidly with trimethylsilyl iodide to give corresponding octyl iodides and trimethylsilyl fluoride.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
107.6 °F - closed cup
flash_point_c
42 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Halogen redistribution reactions between alkyl halides and trimethylsilyl iodide.
Friedrich EC and De Lucca G.
Journal of Organometallic Chemistry, 226(2), 143-148 (1982)
Ervin Sz Kováts et al.
Journal of chromatography. A, 1113(1-2), 206-219 (2006-02-25)
In a paper published in 1992 [K.S. Reddy, J.-Cl. Dutoit, E.sz. Kováts, Pair-wise interactions by gas chromatography. I. Interaction free enthalpies of solutes with non-associated primary alcohol groups, J. Chromatogr. 609 (1992) 229] retention indices and standard chemical potential differences
Kouki Matsubara et al.
Organic letters, 11(8), 1765-1768 (2009-03-14)
An unexpected C-F bond-cleavage reaction of unactivated fluoroalkanes with the well-known Grignard reagents without using metal catalysts has been discovered. For example, a reaction between 1-fluorooctane and phenyl magnesium chloride gave n-octylbenzene in moderate yield. This coupling reaction via the
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