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Merck
CN

283630

乙烯基二茂铁

97%, solid

别名:

Ethenylferrocene

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关于此项目

经验公式(希尔记法):
C12H12Fe
化学文摘社编号:
分子量:
212.07
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
EC Number:
215-041-1
MDL number:
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产品名称

乙烯基二茂铁, 97%

InChI key

LCPVTGDQYVLJHU-UHFFFAOYSA-N

InChI

1S/C7H7.C5H5.Fe/c1-2-7-5-3-4-6-7;1-2-4-5-3-1;/h2-6H,1H2;1-5H;

SMILES string

[Fe].[CH]1[CH][CH][CH][CH]1.C=C[C]2[CH][CH][CH][CH]2

assay

97%

form

solid

reaction suitability

core: iron
reagent type: catalyst

bp

80-85 °C/0.2 mmHg (lit.)

mp

51-53 °C (lit.)

Quality Level

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Application

用乙烯基二茂铁与氨基锂类化合物合成 2-氨甲基二茂铁类化合物。

wgk

WGK 3

pictograms

Flame

signalword

Danger

hcodes

pcodes

Hazard Classifications

Flam. Sol. 1

存储类别

4.1B - Flammable solid hazardous materials

flash_point_f

143.6 °F - closed cup

flash_point_c

62 °C - closed cup

ppe

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Atsunori Hiratsuka et al.
Biosensors & bioelectronics, 21(6), 957-964 (2005-11-01)
We propose a new strategy for constructing a mediator-type biosensor as a Bio-MicroElectroMechanical Systems (BioMEMS) application. A vinylferrocene plasma-polymerized film (PPF) was deposited directly onto the surface of an electrode under dry conditions. The resulting redox film was extremely thin
Joachim Loup et al.
Angewandte Chemie (International ed. in English), 56(45), 14197-14201 (2017-09-19)
Highly enantioselective iron-catalyzed C-H alkylations by inner-sphere C-H activation were accomplished with ample scope. High levels of enantiocontrol proved viable through a novel ligand design that exploits a remote meta-substitution on N-heterocyclic carbenes within a facile ligand-to-ligand H-transfer C-H cleavage.
Ryoji Kurita et al.
Biosensors & bioelectronics, 20(3), 518-523 (2004-10-21)
This paper proposes a very simple procedure for preparing a biocompatible sensor based on a protein (bovine serum albumin, BSA), enzyme and vinylferrocene (VF) composite membrane modified electrode. The membrane was prepared simply by first casting vinylferrocene and then coating
Ceren Kaçar et al.
Analytical and bioanalytical chemistry, 409(11), 2873-2883 (2017-02-12)
Highly sensitive L-lysine enzyme electrodes were constructed by using poly(vinylferrocene)-multiwalled carbon nanotubes-gelatine (PVF/MWCNTs-GEL) and poly(vinylferrocene)-multiwalled carbon nanotubes-gelatine-graphene (PVF/MWCNTs-GEL/GR) composites as sensing interfaces and their performances were evaluated. Lysine oxidase (LO) was immobilized onto the composite modified glassy carbon electrodes (GCE)
Tetrahedron, 63, 761-761 (2007)

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