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Merck
CN

339121

Sigma-Aldrich

乙醇锆(IV)

97%

别名:

Tetraethoxyzirconium, Zirconium ethoxide (Zr(OEt)4 ), Zirconium tetraethoxide

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关于此项目

线性分子式:
Zr(OC2H5)4
化学文摘社编号:
分子量:
271.47
MDL编号:
UNSPSC代码:
12352103
PubChem化学物质编号:
NACRES:
NA.23
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方案

97%

表单

solid

反应适用性

core: zirconium
reagent type: catalyst

沸点

235 °C/5 mmHg (lit.)

SMILES字符串

CCO[Zr](OCC)(OCC)OCC

InChI

1S/4C2H5O.Zr/c4*1-2-3;/h4*2H2,1H3;/q4*-1;+4

InChI key

ASBGGHMVAMBCOR-UHFFFAOYSA-N

一般描述

Zirconium(IV) ethoxide is a colourless to pale yellow liquid widely used as a zirconium precursor. It is highly reactive toward moisture and well-suited for hydrolysis and condensation reactions. The compound is soluble in organic solvents such as alcohols and hydrocarbons, enabling its use in various solution-based synthesis techniques. It thermally decomposes into high-purity zirconium dioxide (ZrO₂), a valuable ceramic material known for its thermal stability, corrosion resistance, and dielectric properties. Zirconium(IV) ethoxide is commonly employed in sol-gel processes, chemical vapor deposition (CVD), and the synthesis of nanomaterials, facilitating the fabrication of uniform thin films, coatings, and advanced ceramic components. Its controlled reactivity, high volatility, and compatibility with diverse synthesis routes make it a versatile and efficient precursor for developing zirconium-based materials.

应用

合成烯烃官能化含锆单体的便捷前体,该单体可生成含锆的杂化聚合物。
  • Zr(OEt)₄ can be used as a: Precursor in the sol-gel synthesis of PMMA/ZrO₂ hybrid. These films exhibit enhanced dielectric properties for flexible electronic applications.
  • Precursor for the synthesis of Li₂ZrO₃ coatings on NCM622 particles.
  • As a precursor in the synthesized of Zirconia nanoparticles (ZrO2NPs) by sol–gel reaction.

特点和优势

  • The purity level (97%) influences the catalytic activity and selectivity, as higher purity typically leads to fewer side reactions and better control over synthesis of polymers.
  • The purity and viscosity of the ethoxide can influence the uniformity and adhesion of the coatings, impacting their performance in various environments.

象形图

FlameExclamation mark

警示用语:

Danger

危险分类

Eye Irrit. 2 - Flam. Sol. 1 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

储存分类代码

4.1B - Flammable solid hazardous materials

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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William J. Evans et al.
Inorganic chemistry, 38(6), 1160-1164 (2001-10-24)
The attachment of pendent olefin groups to oxygen-ligated zirconium complexes using olefin-substituted phenols and alcohols and readily accessible zirconium reagents is described. Syntheses of three crystallographically characterizable complexes isolable in 55-90% yield are reported. Eugenol, HOC(6)H(3)(OMe-2)(CH(2)CH=CH(2)-4) (HOAr) reacts with [Zr(O(i)Pr)(4)(HO(i)Pr)](2)

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