341134
[1,4-双(二苯基膦)丁烷](1,5-环辛二烯)四氟硼酸铑(I)
98%
别名:
[Rh(dppb)(COD)]BF4
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关于此项目
经验公式（希尔记法）:
C36H40BF4P2Rh
化学文摘社编号:
分子量:
724.36
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
MDL number:
Quality Segment
assay
98%
reaction suitability
core: rhodium, reagent type: catalyst
greener alternative product characteristics
Catalysis
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sustainability
Greener Alternative Product
mp
205 °C (dec.) (lit.)
greener alternative category
SMILES string
[Rh+].F[B-](F)(F)F.C1CC=CCCC=C1.C(CCP(c2ccccc2)c3ccccc3)CP(c4ccccc4)c5ccccc5
InChI
1S/C28H28P2.C8H12.BF4.Rh/c1-5-15-25(16-6-1)29(26-17-7-2-8-18-26)23-13-14-24-30(27-19-9-3-10-20-27)28-21-11-4-12-22-28;1-2-4-6-8-7-5-3-1;2-1(3,4)5;/h1-12,15-22H,13-14,23-24H2;1-2,7-8H,3-6H2;;/q;;-1;+1/b;2-1-,8-7-;;
InChI key
YESRLRPURJQQBI-ONEVTFJLSA-N
General description
We are committed to bringing you Greener Alternative Products, which adhere to one of the four categories of Greener Alternatives. This product falls under category 12 PAP and aligns with the Green Chemistry Principle of Catalysis. Click here for more information.
[1,4-Bis(diphenylphosphino)butane](1,5-cyclooctadiene)rhodium(I) tetrafluoroborate is a rhodium-based catalyst used for regioselective hydrogenation and enantioselective reductive amination reactions.
Application
[1,4-Bis(diphenylphosphino)butane](1,5-cyclooctadiene)rhodium(I)tetrafluoroborate can be used as a catalyst for the:
- Regioselective hydrogenation of thebaine to synthesize tetrahydrothebaine.
- Enantioselective reductive amination of α-ketoacids with benzylamines to synthesize α-N-benzylamino acids.
- Stereoselective hydrogenation of α-(hydroxymethyl)-acrylate derivatives to synthesize 3-hydroxy-2-methylpropanoates.
signalword
Warning
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves