345725
2,3,6-三氟苯酚
98%
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关于此项目
线性分子式:
F3C6H2OH
化学文摘社编号:
分子量:
148.08
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
产品名称
2,3,6-三氟苯酚, 98%
InChI
1S/C6H3F3O/c7-3-1-2-4(8)6(10)5(3)9/h1-2,10H
SMILES string
Oc1c(F)ccc(F)c1F
InChI key
QSFGUSFDWCVXNR-UHFFFAOYSA-N
assay
98%
form
solid
mp
33-37 °C (lit.)
functional group
fluoro
Quality Level
Application
2,3,6-Trifluorophenol may be employed as model compound to investigate the site-selective functionalization of halogen-bearing phenols by organometallic approach.
General description
2,3,6-Trifluorophenol is a fluorinated phenol. Biotransformation of 2,3,6-trifluorophenol has been studied by 19FNMR technique.
signalword
Danger
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Flam. Sol. 1 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
4.1B - Flammable solid hazardous materials
wgk
WGK 3
flash_point_f
147.2 °F - closed cup
flash_point_c
64 °C - closed cup
ppe
dust mask type N95 (US), Eyeshields, Gloves
The site-selective functionalization of halogen-bearing phenols: an exercise in diversity-oriented organometallic synthesis.
Marzi E and Schlosser M.
Tetrahedron, 61(13), 3393-3401 (2005)
M G Boersma et al.
Journal of industrial microbiology & biotechnology, 26(1-2), 22-34 (2001-09-11)
Of all NMR-observable isotopes 19F is the one most convenient for studies on the biodegradation of environmental pollutants and especially for fast initial metabolic screening of newly isolated organisms. In the past decade we have identified the 19F NMR characteristics
Matthew G Romei et al.
Science (New York, N.Y.), 367(6473), 76-79 (2020-01-04)
Rotation around a specific bond after photoexcitation is central to vision and emerging opportunities in optogenetics, super-resolution microscopy, and photoactive molecular devices. Competing roles for steric and electrostatic effects that govern bond-specific photoisomerization have been widely discussed, the latter originating
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