359688
Boc-Lys-OH
99%
别名:
Nα-(叔丁氧羰基)-L-赖氨酸, Nα-Boc-L-赖氨酸
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关于此项目
线性分子式:
NH2(CH2)4CH(COOH)NHCOOC(CH3)3
化学文摘社编号:
分子量:
246.30
NACRES:
NA.22
PubChem Substance ID:
eCl@ss:
32160406
UNSPSC Code:
12352209
MDL number:
Beilstein/REAXYS Number:
4252546
产品名称
Boc-Lys-OH, 99%
InChI
1S/C11H22N2O4/c1-11(2,3)17-10(16)13-8(9(14)15)6-4-5-7-12/h8H,4-7,12H2,1-3H3,(H,13,16)(H,14,15)/t8-/m0/s1
SMILES string
CC(C)(C)OC(=O)N[C@@H](CCCCN)C(O)=O
InChI key
DQUHYEDEGRNAFO-QMMMGPOBSA-N
assay
99%
form
solid
optical activity
[α]/D 4.1 to 5.1°, c = 2 in water
reaction suitability
reaction type: Boc solid-phase peptide synthesis
mp
~205 °C (dec.) (lit.)
application(s)
peptide synthesis
Quality Level
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Application
Boc-Lys-OH（Nα-叔丁氧羰基-L-赖氨酸）可作为构建单元用于合成：
- 作为生物标记试剂，应用于基于异三功能肽的连接体分子。
- 合成氮杂环和蒽醌的赖氨酸衍生物。
- Boc-Lys（Bn4-DTPA）-OH，作为前体合成含肽的二乙基三胺五乙酸（DTPA）。
- 二茂铁-氨基酸共轭物，用于开发化学战剂（CWA）传感器。
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
Synthesis of lysine derivatives containing aza-crown ethers and a chromophore unit
Ossowski T, et al.
Tetrahedron Letters, 46(10), 1735-1738 (2005)
Synthesis of Nα-Boc-Nε-tetrabenzyl-DTPA-l-lysine and Nα-Fmoc-Nε-tetra-t-butyl-DTPA-l-lysine, building blocks for solid phase synthesis of DTPA-containing peptides
Davies JS and Al-Jamri L
Journal of Peptide Science, 8(12), 663-670 (2002)
A novel heterotrifunctional peptide-based cross-linking reagent for facile access to bioconjugates. Applications to peptide fluorescent labelling and immobilisation
Clave G, et al.
Organic & Biomolecular Chemistry, 6(17), 3065-3078 (2008)
Carla Kühn et al.
Molecular nutrition & food research, 62(20), e1800588-e1800588 (2018-08-10)
Different metabolic and excretion pathways of the benzyl glucosinolate breakdown products benzyl isothiocyanate and benzyl cyanide are investigated to obtain information about their multiple fate after ingestion. Detailed focus is on the so far underestimated transformation/excretion pathways-protein conjugation and exhalation.
Carla Kühn et al.
Journal of agricultural and food chemistry, 66(26), 6727-6733 (2018-06-09)
Glucosinolates and their breakdown products, especially isothiocyanates (ITCs), are hypothesized to exert a broad range of bioactivities. However, physiological mechanisms are not yet completely understood. In this study, formation of protein conjugates after incubation with benzyl isothiocyanate (BITC) was investigated
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