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Merck
CN

412910

甲基三氧苯 (VII)

Re 71.0-76.0 %, solid

别名:

MTO, 甲基铼(VII)三氧化物

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关于此项目

线性分子式:
CH3ReO3
化学文摘社编号:
分子量:
249.24
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
MDL number:
Beilstein/REAXYS Number:
3927932
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产品名称

甲基三氧苯 (VII), Re 71.0-76.0 %

InChI

1S/CH3.3O.Re/h1H3;;;;

SMILES string

C[Re](=O)(=O)=O

InChI key

PQTLALPZRPFYIT-UHFFFAOYSA-N

form

solid

composition

Re, 71.0-76.0%

reaction suitability

core: rhenium, reagent type: catalyst

mp

111 °C (lit.)

Quality Level

Application

强效催化氧化剂,用于将各种溶剂中的烯烃转化为环氧化物,将 2-甲基萘转化为 2-甲基-1,4-萘醌(维生素 K3)。
催化氧化剂,与尿素过氧化氢共同用于将亚胺高效转化为硝酮。
各种条件下的有效抗氧化剂。

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Bee Hong Soon et al.
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Veronika Huntosova et al.
Molecules (Basel, Switzerland), 26(2) (2021-01-23)
Detection of tissue and cell oxygenation is of high importance in fundamental biological and in many medical applications, particularly for monitoring dysfunction in the early stages of cancer. Measurements of the luminescence lifetimes of molecular probes offer a very promising
Steven W Baldwin et al.
Organic letters, 6(10), 1653-1656 (2004-05-07)
Cycloaddition reactions between a new homochiral imidazolone-derived nitrone afford cycloadducts in high yield and with high stereoselectivity. Subsequent cycloadduct elaboration affords the gamma-lactones of gamma-hydroxy-alpha-amino acids as well as the optically pure amino acids themselves.
Shaunak Sen et al.
ACS synthetic biology, 6(8), 1461-1470 (2017-04-25)
Biomolecular temperature sensors can be used for efficient control of large-volume bioreactors, for spatiotemporal imaging and control of gene expression, and to engineer robustness to temperature in biomolecular circuit design. Although RNA-based sensors, called "thermometers", have been investigated in both
Inorganic Chemistry, 32, 4517-4517 (1993)

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