412910
甲基三氧苯 (VII)
Re 71.0-76.0 %, solid
别名:
MTO, 甲基铼(VII)三氧化物
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关于此项目
线性分子式:
CH3ReO3
化学文摘社编号:
分子量:
249.24
Beilstein:
3927932
MDL编号:
UNSPSC代码:
12161600
PubChem化学物质编号:
NACRES:
NA.22
产品名称
甲基三氧苯 (VII), Re 71.0-76.0 %
表单
solid
质量水平
组成
Re, 71.0-76.0%
反应适用性
core: rhenium
reagent type: catalyst
mp
111 °C (lit.)
SMILES字符串
C[Re](=O)(=O)=O
InChI
1S/CH3.3O.Re/h1H3;;;;
InChI key
PQTLALPZRPFYIT-UHFFFAOYSA-N
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应用
强效催化氧化剂，用于将各种溶剂中的烯烃转化为环氧化物，将 2-甲基萘转化为 2-甲基-1,4-萘醌（维生素 K3）。
催化氧化剂，与尿素过氧化氢共同用于将亚胺高效转化为硝酮。
各种条件下的有效抗氧化剂。
催化氧化剂，与尿素过氧化氢共同用于将亚胺高效转化为硝酮。
各种条件下的有效抗氧化剂。
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Gloves, type N95 (US)
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Detection of tissue and cell oxygenation is of high importance in fundamental biological and in many medical applications, particularly for monitoring dysfunction in the early stages of cancer. Measurements of the luminescence lifetimes of molecular probes offer a very promising
Steven W Baldwin et al.
Organic letters, 6(10), 1653-1656 (2004-05-07)
Cycloaddition reactions between a new homochiral imidazolone-derived nitrone afford cycloadducts in high yield and with high stereoselectivity. Subsequent cycloadduct elaboration affords the gamma-lactones of gamma-hydroxy-alpha-amino acids as well as the optically pure amino acids themselves.
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