431338
硝酸铈(IV)铵
99.99%
别名:
硝酸铈铵
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关于此项目
线性分子式:
Ce(NH4)2(NO3)6
化学文摘社编号:
分子量:
548.22
UNSPSC Code:
12352302
PubChem Substance ID:
EC Number:
240-827-6
MDL number:
InChI key
WIBGOERAEYJBOT-UHFFFAOYSA-N
InChI
1S/Ce.2HNO3.4NO3.2H3N/c;6*2-1(3)4;;/h;2*(H,2,3,4);;;;;2*1H3/q+4;;;4*-1;;
SMILES string
N.N.[Ce+4].O[N+]([O-])=O.O[N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O
assay
99.99%
reaction suitability
reagent type: oxidant
impurities
≤0.05% insol. dil. H2SO4, <100 ppm total metallic impurities
anion traces
chloride (Cl-): ≤0.01%, phosphate (PO43-): ≤0.02%
cation traces
Fe: ≤0.005%
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Application
提供通过温和条件下氧化丙二酸盐得到丙醇二酸衍生物的一种新途径。
Features and Benefits
符合 ACS 试剂规范。
signalword
Danger
Hazard Classifications
Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Met. Corr. 1 - Ox. Sol. 2 - Skin Corr. 1B - Skin Sens. 1A
存储类别
5.1B - Oxidizing hazardous materials
wgk
WGK 3
ppe
Eyeshields, Gloves, type P3 (EN 143) respirator cartridges
法规信息
新产品
此项目有
Nair, V. et al.
Tetrahedron Letters, 39, 2801-2801 (1998)
David A Evans et al.
Organic letters, 8(24), 5669-5671 (2006-11-17)
The ceric ammonium nitrate promoted oxidations of 4,5-diphenyloxazoles and oxazoles with various substitution patterns have been investigated. This transformation results in the formation of the corresponding imide in good yield and tolerates a wide variety of functional groups and substituents
Douglas B Grotjahn et al.
Journal of the American Chemical Society, 133(47), 19024-19027 (2011-11-09)
Organometallic iridium complexes have been reported as water oxidation catalysts (WOCs) in the presence of ceric ammonium nitrate (CAN). One challenge for all WOCs regardless of the metal used is stability. Here we provide evidence for extensive modification of many
Somak Paul et al.
Carbohydrate research, 339(13), 2197-2204 (2004-09-01)
Synthesis of 2-deoxy-1-thioglycosides from glycals, mediated by catalytic amounts of ceric ammonium nitrate is reported. Apart from the 2-deoxy-1-thioglycosides, formation of the 2,3-unsaturated enose, corresponding to the Ferrier product, is also observed, especially for the glucal substrates. A radical oxocarbenium
Mazaahir Kidwai et al.
Chemical & pharmaceutical bulletin, 58(10), 1320-1323 (2010-10-12)
An environment friendly method for the synthesis of 2-oxo/thioxooctahydroquinazolin-5-one derivatives has been devised using Ceric ammonium nitrate (CAN) as catalyst and polyethylene glycol (PEG) as solvent. The cytotoxic effect of these compounds was studied on U87 human glioma cells, compounds
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