436011
磷酸铁(III) 二水合物
Fe 29%, powder
别名:
二水磷酸铁
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关于此项目
线性分子式:
FePO4 · 2H2O
化学文摘社编号:
分子量:
186.85
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
MDL number:
产品名称
磷酸铁(III) 二水合物, Fe 29 %
SMILES string
O.O.[Fe+3].[O-]P([O-])([O-])=O
InChI
1S/Fe.H3O4P.2H2O/c;1-5(2,3)4;;/h;(H3,1,2,3,4);2*1H2/q+3;;;/p-3
InChI key
BMTOKWDUYJKSCN-UHFFFAOYSA-K
form
powder
composition
Fe, 29%
reaction suitability
core: iron, reagent type: ligand
reaction type: Cross Couplings
functional group
amine, phosphine
Quality Level
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Application
磷酸铁(III)二水合物(FePO4 x 2H2O)可作为催化剂用于：
还用于合成碳包覆磷酸铁锂(LiFePO4)，作为锂离子电池的正极材料。它还是制备磷酸盐玻璃纤维的主要原料。
- 通过醛、β-酮酸酯和尿素/硫脲的一锅三组分Biginelli反应生成3,4-二氢嘧啶-2(1H)-酮和硫酮。
- 通过异丁酸甲酯(MIB)的氧化脱氢反应生成甲基丙烯酸甲酯(MMA)。
还用于合成碳包覆磷酸铁锂(LiFePO4)，作为锂离子电池的正极材料。它还是制备磷酸盐玻璃纤维的主要原料。
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
Synthesis and degradation of sodium iron phosphate glasses and their in vitro cell response
Parsons AJ, et al.
Journal of Biomedical Materials Research Part A, 71(2), 283-291 (2004)
Miran Gaberscek et al.
Physical chemistry chemical physics : PCCP, 9(15), 1815-1820 (2007-04-07)
We try to identify the rate-determining step of electrochemical kinetics of a LiFePO(4)-carbon composite electrode by varying the mass of electrode and, additionally, by varying the charge-discharge current in a wide range. It is shown that the reversible capacity is
A graphene-amorphous FePO4 hollow nanosphere hybrid as a cathode material for lithium ion batteries.
Yajing Yin et al.
Chemical communications (Cambridge, England), 48(15), 2137-2139 (2012-01-17)
Amorphous FePO(4) hollow nanospheres were directly grown on graphene for use as a cathode material in lithium ion batteries. This hybrid exhibits high rate capability and good cycle stability because of efficient Li(+) ion diffusion through the thin wall of
Wei Wang et al.
Chemical communications (Cambridge, England), 48(58), 7289-7291 (2012-06-16)
Novel iron phosphates microflowers which show SOD-like and peroxidase-like mimic activities were prepared, suggesting potential applications as a biocatalyst and a biosensor for H(2)O(2).
Structural and electrochemical study of a new crystalline hydrated iron (III) phosphate FePO4
Marx N, et al.
Chemistry of Materials, 22(5), 1854-1861 (2010)
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