436011
磷酸铁(III) 二水合物
Fe 29%, powder
别名:
二水磷酸铁
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关于此项目
线性分子式:
FePO4 · 2H2O
化学文摘社编号:
分子量:
186.85
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
MDL number:
产品名称
磷酸铁(III) 二水合物, Fe 29 %
SMILES string
O.O.[Fe+3].[O-]P([O-])([O-])=O
InChI
1S/Fe.H3O4P.2H2O/c;1-5(2,3)4;;/h;(H3,1,2,3,4);2*1H2/q+3;;;/p-3
InChI key
BMTOKWDUYJKSCN-UHFFFAOYSA-K
form
powder
composition
Fe, 29%
reaction suitability
core: iron
reagent type: ligand
reaction type: Cross Couplings
functional group
amine
phosphine
Quality Level
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Application
磷酸铁(III)二水合物(FePO4 x 2H2O)可作为催化剂用于：
还用于合成碳包覆磷酸铁锂(LiFePO4)，作为锂离子电池的正极材料。它还是制备磷酸盐玻璃纤维的主要原料。
- 通过醛、β-酮酸酯和尿素/硫脲的一锅三组分Biginelli反应生成3,4-二氢嘧啶-2(1H)-酮和硫酮。
- 通过异丁酸甲酯(MIB)的氧化脱氢反应生成甲基丙烯酸甲酯(MMA)。
还用于合成碳包覆磷酸铁锂(LiFePO4)，作为锂离子电池的正极材料。它还是制备磷酸盐玻璃纤维的主要原料。
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
A novel process to recycle spent LiFePO4 for synthesizing LiFePO4/C hierarchical microflowers.
Bian D, et al.
Electrochimica Acta, 190, 134-140 (2016)
Jun-Il Kim et al.
Journal of nanoscience and nanotechnology, 12(11), 8475-8480 (2013-02-21)
A composite of LiFePO4 and MgO-templated disordered mesoporous carbon was prepared through infiltrating a LiFePO4 precursor solution into the mesoporous carbon and growing LiFePO4 nanocrystals in the pore of the carbon. Transmission electron microscope (TEM) and scanning electron microscope (SEM)
Preparation and Electrochemical Properties of the Spongelike Melamine Formaldehyde-Poly (vinyl alcohol)/LiFePO4 Porous Composite as the Lithium-Battery Cathode
Roddecha S, et al.
Industrial & Engineering Chemistry Research, 58(2), 632-642 (2018)
Synthesis of porous amorphous FePO4 nanotubes and their lithium storage properties.
Ren Cai et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 19(5), 1568-1572 (2013-01-03)
Miran Gaberscek et al.
Physical chemistry chemical physics : PCCP, 9(15), 1815-1820 (2007-04-07)
We try to identify the rate-determining step of electrochemical kinetics of a LiFePO(4)-carbon composite electrode by varying the mass of electrode and, additionally, by varying the charge-discharge current in a wide range. It is shown that the reversible capacity is
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