547980
三[N,N-双(三甲基硅烷)胺]钐(III)
98%, solid
别名:
1,1,1-Trimethyl-N-(trimethylsilyl)silanamine samarium(III) salt, Tris(1,1,1,3,3,3-hexamethyldisilazanato)samarium
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关于此项目
线性分子式:
Sm(N(Si(CH3)3)2)3
化学文摘社编号:
分子量:
631.51
MDL编号:
UNSPSC代码:
12161600
PubChem化学物质编号:
NACRES:
NA.22
产品名称
三[N,N-双(三甲基硅烷)胺]钐(III), 98%
方案
98%
表单
solid
反应适用性
core: samarium
reagent type: catalyst
mp
93-106 °C (lit.)
SMILES字符串
C[Si](C)(C)N([Sm](N([Si](C)(C)C)[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C)[Si](C)(C)C
InChI
1S/3C6H18NSi2.Sm/c3*1-8(2,3)7-9(4,5)6;/h3*1-6H3;/q3*-1;+3
InChI key
MUFPZLRACJKLCI-UHFFFAOYSA-N
应用
Reactant for synthesis of:
Catalyst for:
- Heterobimetallic samarium(III) complexes
- Binuclear lanthanide complexes
Catalyst for:
- Coordination polymerization of renewable butyrolactone-based vinyl monomers
- Intramolecular hydroamination of non-activated alkenes
- Chiral functionalization of isoxazoles
- Enantioselective hydroamination / cyclization
警示用语：
Danger
危险声明
危险分类
Flam. Sol. 1 - Skin Corr. 1B - Water-react 2
补充剂危害
储存分类代码
4.3 - Hazardous materials which set free flammable gases upon contact with water
WGK
WGK 3
闪点(°F)
36.0 °F - closed cup
闪点(°C)
2.2 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
法规信息
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