593095
(2-甲基烯丙基)膦酸二乙酯
97%
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关于此项目
线性分子式:
(C2H5O)2POCH2C(=CH2)CH3
化学文摘社编号:
分子量:
192.19
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352108
MDL number:
Assay:
97%
assay
97%
reaction suitability
reaction type: C-C Bond Formation
refractive index
n
bp
62 °C/0.1 mmHg (lit.)
density
1.013 g/mL at 25 °C (lit.)
functional group
phosphonate
SMILES string
CCOP(=O)(CC(C)=C)OCC
InChI
1S/C8H17O3P/c1-5-10-12(9,11-6-2)7-8(3)4/h3,5-7H2,1-2,4H3
InChI key
QOZGSMHGXZMADD-UHFFFAOYSA-N
General description
Application
Diethyl (2-methylallyl)phosphonate can be used as a reagent in the Horner-Wadsworth-Emmons reaction to form conjugated carbon–carbon double bonds.
It can also be used as a reactant for:
It can also be used as a reactant for:
- Enantioselective total synthesis of 10-isocyano-4-cadinene as antifouling agent.
- Regiospecific preparation of 4-oxo-2-alkenylphosphonates (OAP) via silylation followed by Friedel-Crafts acylation and isomerization. OAP can serve as building blocks for the construction of polyethylenic chains.
- The synthesis of azaphosphone as a potent analgesic/anti-inflammatory agents.
Reactant for:
- Enantioselective synthesis of 10-isocyano-4-cadinene and its stereoisomers with antifouling activity
- Preparation of 4-Oxo-2-alkenylphosphonates via silylation followed by regiospecific Friedel-Crafts acylation and isomerization
signalword
Warning
hcodes
pcodes
Hazard Classifications
Eye Irrit. 2
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
>230.0 °F - closed cup
flash_point_c
> 110 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter