产品名称
Lindlar 催化剂,
form
solid
reaction suitability
core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
Quality Level
Application
林德拉催化剂是一种非均相催化剂，主要用于将炔烃选择性氢化成烯烃。
它还可有效催化：
它还可有效催化：
- 三键选择性氢化成顺式双键
- 聚烯烃的单氢化
- 叠氮化物氢化成胺
Other Notes
碳酸钙上 ~ 5% 钯；遇铅中毒。
signalword
Danger
Hazard Classifications
Aquatic Chronic 1 - Flam. Sol. 1 - Lact. - Repr. 1A - STOT RE 2
target_organs
Central nervous system,Blood,Immune system,Kidney
存储类别
4.1B - Flammable solid hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
Intermetallic Pd1-Zn1 nanoparticles in the selective liquid-phase hydrogenation of substituted alkynes.
Mashkovsky IS, et al.
Kinetics and Catalysis, 58(4), 480-491 (2017)
Effect of lead acetate in the preparation of the Lindlar catalyst.
Ulan JG, et al.
The Journal of Organic Chemistry, 52(14), 3126-3132 (1987)
Chemoselective catalytic hydrogenation of alkenes by Lindlar catalyst.
Ghosh AK & Krishnan K.
Tetrahedron Letters, 39(9), 947-948 (1998)
A new convenient approach to the preparation of Z-1-alkenylboronates by the cis-Hydrogenation of 1-Alkynyldiisopropoxyboranes.
Srebnik M, et al.
Tetrahedron Letters, 29(22), 2635-2638 (1988)
The Lindlar Catalyst Revitalized: A Highly Chemoselective Method for the Direct Conversion of Azides to N-(tert-Butoxycarbonyl) amines.
Reddy PG, et al.
European Journal of Organic Chemistry, 2002(22), 3740-3743 (2002)
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