产品名称
Lindlar 催化剂,
form
solid
reaction suitability
core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
Quality Level
Application
林德拉催化剂是一种非均相催化剂，主要用于将炔烃选择性氢化成烯烃。
它还可有效催化：
它还可有效催化：
- 三键选择性氢化成顺式双键
- 聚烯烃的单氢化
- 叠氮化物氢化成胺
Other Notes
碳酸钙上 ~ 5% 钯；遇铅中毒。
signalword
Danger
Hazard Classifications
Aquatic Chronic 1 - Flam. Sol. 1 - Lact. - Repr. 1A - STOT RE 2
target_organs
Central nervous system,Blood,Immune system,Kidney
存储类别
4.1B - Flammable solid hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
Effect of lead acetate in the preparation of the Lindlar catalyst.
Ulan JG, et al.
The Journal of Organic Chemistry, 52(14), 3126-3132 (1987)
Intermetallic Pd1-Zn1 nanoparticles in the selective liquid-phase hydrogenation of substituted alkynes.
Mashkovsky IS, et al.
Kinetics and Catalysis, 58(4), 480-491 (2017)
A new convenient approach to the preparation of Z-1-alkenylboronates by the cis-Hydrogenation of 1-Alkynyldiisopropoxyboranes.
Srebnik M, et al.
Tetrahedron Letters, 29(22), 2635-2638 (1988)
Chemoselective catalytic hydrogenation of alkenes by Lindlar catalyst.
Ghosh AK & Krishnan K.
Tetrahedron Letters, 39(9), 947-948 (1998)
The Lindlar Catalyst Revitalized: A Highly Chemoselective Method for the Direct Conversion of Azides to N-(tert-Butoxycarbonyl) amines.
Reddy PG, et al.
European Journal of Organic Chemistry, 2002(22), 3740-3743 (2002)
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