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Merck
CN

630551

(2-乙基己基)溴化镁 溶液

1.0 M in diethyl ether

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关于此项目

经验公式(希尔记法):
C8H17BrMg
化学文摘社编号:
分子量:
217.43
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352103
MDL number:
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InChI

1S/C8H17.BrH.Mg/c1-4-6-7-8(3)5-2;;/h8H,3-7H2,1-2H3;1H;/q;;+1/p-1

SMILES string

CCCCC(CC)C[Mg]Br

InChI key

NDCJRLBSQQDNOO-UHFFFAOYSA-M

reaction suitability

reaction type: Grignard Reaction

concentration

1.0 M in diethyl ether

density

0.863 g/mL at 25 °C

Quality Level

Application

(2-Ethylhexyl)magnesium bromide (Grignard reagent) can be used in the synthesis of:       
  • 3-ethyl-N,N-dimethyl-1-(pyridin-2-yl)heptan-1-amine, a pyridyl amine ligand, which is used in the polymerization of olefins.   
  •  Diphenylbis(2-ethylhexyl) germane from diphenylgermanium dichloride by Grignard addition reaction.       
  • Dichloro (dodecyl) 2-ethylhexylsilane, a key intermediate that is used in the preparation of silafluorene-based copolymers.

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3

target_organs

Respiratory system

supp_hazards

存储类别

3 - Flammable liquids

wgk

WGK 3

flash_point_f

-13.0 °F - closed cup

flash_point_c

-25 °C - closed cup

法规信息

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分析证书(COA)

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A practical synthesis of N, N-dimethyl-(6-arylpyrid-2-yl) alkylamines
Faler, Catherine A
Tetrahedron Letters, 51(42), 5621-5623 (2010)
A low band gap co-polymer of dithienogermole and 2, 1, 3-benzothiadiazole by Suzuki polycondensation and its application in transistor and photovoltaic cells
Fei Z, et al.
Journal of Materials Chemistry, 21(40), 16257-16263 (2011)
Chinna D Bathula et al.
Journal of nanoscience and nanotechnology, 14(8), 6002-6007 (2015-05-06)
A series of silafluorene-based copolymers, poly[9-(2-ethylhexyl)-9-dodecyl-silafluorene-2,7-diyl-alt-5,5-(4',7'-di-2-thienyl-2',1',3'-benzothiadiazole)] (P1), poly[9-(2-ethylhexyl)-9-dodecyl-silafluorene-2,7-diyl-alt-2,5-bis-(thiophene-2-yl)thiazolo [5,4-d]thiazole] (P2), and poly[9-(2-ethylhexyl)-9-dodecyl-silafluorene-2,7-diyl-alt-5,5-(5',8'-di-2-thienyl-2,3-bis(4-octyloxyl)phenyl)quinoxaline] (P3), were synthesized and used as donor materials in polymer solar cells (PSCs). The optical, electrochemical, and photovoltaic properties of the copolymers were investigated. The results indicate that

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