reaction suitability
core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
Application
Catalysis Screening Kits
A kit of 5 Pd EnCat® catalysts which are micro-encapsulated palladium acetate catalysts with or without phosphine ligands which facilitate carbon-carbon bond forming processes as well as the removal of palladium metal contamination.
A kit of 5 Pd EnCat® catalysts which are micro-encapsulated palladium acetate catalysts with or without phosphine ligands which facilitate carbon-carbon bond forming processes as well as the removal of palladium metal contamination.
Legal Information
EnCat is a registered trademark of Reaxa Ltd.
试剂盒组分也可单独购买
产品编号
说明
化学品安全说明书
- 644692Pd EnCat® TOTP30, extent of labeling: 0.4 mmol/g Pd loading, TOTP 0.5, Pd 1.0 1 g
- 644706Pd EnCat® TPP30, extent of labeling: 0.4 mmol/g Pd loading, TPP 0.8, Pd 1.0 1 g
- 644714Pd EnCat® 30, extent of labeling: 0.4 mmol/g Pd loading 1 g
- 644722Pd EnCat® 40, extent of labeling: 0.4 mmol/g Pd loading 1 g
- 658693Pd(II) EnCat® BINAP30, extent of labeling: 0.39 mmol/g Pd loading, BINAP 0.25, Pd 1.0 1 g
signalword
Danger
Hazard Classifications
Aquatic Chronic 3 - Carc. 2 - Eye Irrit. 2 - Flam. Sol. 2 - Repr. 1B - Skin Irrit. 2 - STOT RE 2 Inhalation - STOT RE 2 Oral
target_organs
Liver,Kidney, Nervous system
存储类别
4.1B - Flammable solid hazardous materials
flash_point_f
-9.4 - -7.6 °F
flash_point_c
-23 - -22 °C
法规信息
新产品
此项目有
Jin-Quan Yu et al.
Chemical communications (Cambridge, England), (6), 678-679 (2003-04-22)
A robust and recyclable palladium catalyst [Pd0EnCat] has been prepared by ligand exchange of polyurea-encapsulated palladium(II) acetate with formic acid, resulting in deposition of Pd(0) in the support material; Pd0EnCat is shown to be a highly efficient transfer hydrogenation catalyst
Steven V Ley et al.
Organic letters, 5(24), 4665-4668 (2003-11-25)
[reaction: see text] Pd nanoparticles (approximately 2 nm in size) microencapsulated in polyurea is an efficient and recyclable catalyst for reductive ring-opening hydrogenolysis of epoxides, using either HCOOH/Et(3)N or H(2) as a hydrogen donor.
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