670359
乙酰基硫甲基-硼烷二苯基膦复合物
≥98.0%
别名:
(T-4)-[S-[(Diphenylphosphino-κP)methyl] ethanethioate]trihydroboron
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关于此项目
经验公式（希尔记法）:
C15H18BOPS
化学文摘社编号:
分子量:
288.15
UNSPSC Code:
12352200
PubChem Substance ID:
NACRES:
NA.22
assay
≥98.0%
form
solid
reaction suitability
reaction type: click chemistry, reagent type: ligand
reaction type: Staudinger Reaction
mp
52-55 °C
functional group
phosphine
storage temp.
2-8°C
SMILES string
B.CC(=O)SCP(c1ccccc1)c2ccccc2
InChI
1S/C15H15OPS.BH3/c1-13(16)18-12-17(14-8-4-2-5-9-14)15-10-6-3-7-11-15;/h2-11H,12H2,1H3;1H3
InChI key
MXPNVFCCEGQGEN-UHFFFAOYSA-N
Application
- Traceless Staudinger ligation reagent with borane protecting group.
- The borane group stabilizes the phosphine against oxidation and can be easily removed with mild basic or acidic conditions to yield the active phosphine.
- After reaction with an azide, the phosphine is eliminated in the presence of water to yield a native amide bond.
- Used in the synthesis of cyclic peptides.
Packaging
Bottomless glass bottle. Contents are inside inserted fused cone.
Legal Information
授权后方可销售，仅供研发使用。美国专利 6,974,884 和相关专利申请
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves