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Merck
CN

685984

氢化铝钠

greener alternative

hydrogen-storage grade

别名:

四氢化铝钠

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关于此项目

线性分子式:
NaAlH4
化学文摘社编号:
分子量:
54.00
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
26111700
EC Number:
237-400-1
MDL number:
Assay:
93%
Form:
powder
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grade

hydrogen-storage grade

assay

93%

form

powder

reaction suitability

reagent type: reductant

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

greener alternative category

SMILES string

[Na+].[AlH4-]

InChI

1S/Al.Na.4H/q-1;+1;;;;

InChI key

MNYCIYRTKITUKR-UHFFFAOYSA-N

General description

Reaction kinetics of sodium aluminum hydrides may be improved by mechanical grinding or chemical modification.This may result in achieving reversible hydrogen storage at lower temperatures (80-140oC). It may behave as a reducing agent.
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

Application

NaAlH4 may be used in the deoxygenative dimerization of carbonyls and alcohols and in hydroalumination of alkenes and alkynes.
Sodium aluminum hydride (NaAlH4) can be used as a hydrogen storage material with a hydrogen content of 5.6%. It can be doped with titanium (Ti) for further use in reversible hydrogen storage.


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signalword

Danger

supp_hazards

存储类别

4.3 - Hazardous materials which set free flammable gases upon contact with water

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

Hazard Classifications

Acute Tox. 4 Oral - Skin Corr. 1B - Water-react. 2

法规信息

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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商品

Mechanochemical Effect of Severe Plastic Deformations: Metal Alloys, Hydrides and Molecular Solids


Gugelchuk M, et al. et al.
e-EROS Encyclopedia of Reagents for Organic Synthesis. (2009)
X-ray absorption study of Ti-activated sodium aluminum hydride
Graetz J, et al.
Applied Physics Letters, 85(3), 500-502 (2004)
Effect of graphite as a co-dopant on the dehydrogenation and hydrogenation kinetics of Ti-doped sodium aluminum hydride
Wang J, et al.
Journal of alloys and compounds, 395(1-2), 252-262 (2005)



全球贸易项目编号

货号GTIN
685984-10G04061832759265