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线性分子式:
NaAlH4
化学文摘社编号:
分子量:
54.00
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
26111700
EC Number:
237-400-1
MDL number:
Assay:
93%
Form:
powder
InChI key
MNYCIYRTKITUKR-UHFFFAOYSA-N
InChI
1S/Al.Na.4H/q-1;+1;;;;
SMILES string
[Na+].[AlH4-]
grade
hydrogen-storage grade
assay
93%
form
powder
reaction suitability
reagent type: reductant
greener alternative product characteristics
Design for Energy Efficiency
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greener alternative category
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General description
Reaction kinetics of sodium aluminum hydrides may be improved by mechanical grinding or chemical modification.This may result in achieving reversible hydrogen storage at lower temperatures (80-140oC). It may behave as a reducing agent.
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Application
NaAlH4 may be used in the deoxygenative dimerization of carbonyls and alcohols and in hydroalumination of alkenes and alkynes.
Sodium aluminum hydride (NaAlH4) can be used as a hydrogen storage material with a hydrogen content of 5.6%. It can be doped with titanium (Ti) for further use in reversible hydrogen storage.
signalword
Danger
hcodes
supp_hazards
存储类别
4.3 - Hazardous materials which set free flammable gases upon contact with water
wgk
WGK 1
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Hazard Classifications
Acute Tox. 4 Oral - Skin Corr. 1B - Water-react. 2
法规信息
监管及禁止进口产品
此项目有
Effect of graphite as a co-dopant on the dehydrogenation and hydrogenation kinetics of Ti-doped sodium aluminum hydride
Wang J, et al.
Journal of alloys and compounds, 395(1-2), 252-262 (2005)
Carbon nanostructures as catalyst for improving the hydrogen storage behavior of sodium aluminum hydride
Hudson MSL, et al.
International Journal of Hydrogen Energy, 37(3), 2750-2755 (2012)
X-ray absorption study of Ti-activated sodium aluminum hydride
Graetz J, et al.
Applied Physics Letters, 85(3), 500-502 (2004)
Gugelchuk M, et al. et al.
e-EROS Encyclopedia of Reagents for Organic Synthesis. (2009)
Development of catalytically enhanced sodium aluminum hydride as a hydrogen-storage material
Jensen CM and Gross KJ
Applied Physics. A, Materials Science & Processing, 72(2), 213-219 (2001)
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Mechanochemical Effect of Severe Plastic Deformations: Metal Alloys, Hydrides and Molecular Solids
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