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线性分子式:
Mg(BH4)2
化学文摘社编号:
分子量:
53.99
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
26111700
MDL number:
InChI
1S/2BH4.Mg/h2*1H4;/q2*-1;+2
SMILES string
[BH4-].[BH4-].[Mg++]
InChI key
BAJRVYFABMRJEO-UHFFFAOYSA-N
assay
95%
form
powder
reaction suitability
reagent type: reductant
greener alternative product characteristics
Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.
sustainability
Greener Alternative Product
greener alternative category
, Enabling
General description
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硼氢化镁(Mg(BH4)2) 是一种储氢材料, 具有14.8%左右的高质量百分比和112 g / L的体积氢密度。它具有较低的氢释放温度和可逆性。Mg(BH4)2可用作可充电镁电池的电解质材料。它的非溶剂化形式可以通过MgCl2和 MBH4之间的固态交换反应获得。
signalword
Danger
Hazard Classifications
Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Skin Corr. 1B - Water-react 2
存储类别
4.3 - Hazardous materials which set free flammable gases upon contact with water
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
High concentration magnesium borohydride/tetraglyme electrolyte for rechargeable magnesium batteries
Tuerxun F, et al.
Journal of Power Sources, 276, 255-261 (2015)
Magnesium borohydride: synthesis and crystal structure
Cerny R, et al.
Angewandte Chemie (International ed. in English), 46(30), 5765-5767 (2007)
Magnesium borohydride as a hydrogen storage material: properties and dehydrogenation pathway of unsolvated Mg (BH 4) 2
Soloveichik GL, et al.
International Journal of Hydrogen Energy, 34(2), 916-928 (2009)
First-principles prediction of a ground state crystal structure of magnesium borohydride.
Ozolins VEH,et al.
Physical Review Letters, 100(13) (2008)
Magnesium borohydride: synthesis and crystal structure.
Cerny R, et al.
Angewandte Chemie (International Edition in English), 119(30), 5867-5869 (2007)
商品
An article about metal borohydrides as hydrogen storage materials
Mechanochemical Effect of Severe Plastic Deformations: Metal Alloys, Hydrides and Molecular Solids
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