900943
氯(4-氰基苯基)[(R)-1-[(S)-2-(二环己基膦基)二茂铁基]乙基二环已基膦]镍(II)
powder or solid
别名:
SK-J003-1n
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选择尺寸
关于此项目
经验公式（希尔记法）:
C43H60ClFeNNiP2
化学文摘社编号:
分子量:
802.88
MDL number:
UNSPSC Code:
12352103
NACRES:
NA.22
产品名称
氯(4-氰基苯基)[(R)-1-[(S)-2-(二环己基膦基)二茂铁基]乙基二环已基膦]镍(II),
SMILES string
Cl[Ni+2]C1=CC=C(C#N)C=C1.C[C@@H](P(C2CCCCC2)C3CCCCC3)[C]4[C][C][C][C]4P(C5CCCCC5)C6CCCCC6.[C]7[C][C][C][C]7.[Fe]
form
powder or solid
reaction suitability
core: nickel
reaction type: Cross Couplings
reagent type: catalyst
reaction type: Asymmetric synthesis
Quality Level
Application
Amination of aryl chlorides, bromides and sulfonates with ammonia. Amination of aryl carbamates with ammonia or ammonium salts.
signalword
Warning
hcodes
Hazard Classifications
Aquatic Chronic 2 - Repr. 2 - Skin Irrit. 2
存储类别
4.1B - Flammable solid hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Nickel?Catalyzed Amination of Aryl Chlorides with Ammonia or Ammonium Salts.
Green R A and Hartwig J F
Angewandte Chemie (International Edition in English), 54(12), 3768-3772 (2015)
Ni?Catalyzed Amination Reactions: An Overview.
Marin M, et al.
Chemical Record, 16(4), 1819-1832 (2016)
Evaluating 1, 1?-Bis (phosphino) ferrocene Ancillary Ligand Variants in the Nickel-Catalyzed C?N Cross-Coupling of (Hetero) aryl Chlorides.
Clark J S, et al.
Organometallics, 36(3), 679-686 (2017)
Nickel?Catalyzed Monoarylation of Ammonia.
Borzenko A, et al.
Angewandte Chemie (International Edition in English), 54(12), 3773-3777 (2015)
Sarah Z Tasker et al.
Nature, 509(7500), 299-309 (2014-05-16)
Tremendous advances have been made in nickel catalysis over the past decade. Several key properties of nickel, such as facile oxidative addition and ready access to multiple oxidation states, have allowed the development of a broad range of innovative reactions.
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