主要文件

查看所有文档

902772

(Diacetoxyiodo)benzene solution

Name: (Diacetoxyiodo)benzene solution
Brand: ALDRICH

0.50 M solution in DCM

别名:

Iodobenzene diacetate, Iodosobenzene diacetate, Phenyl-iodanediyl diacetate

登录查看组织和合同定价。

选择尺寸

变更视图

关于此项目

线性分子式:

C₁₀H₁₁IO₄

化学文摘社编号:

3240-34-4

UNSPSC Code:

12352002

MDL number:

MFCD00008692

技术服务

需要帮助？我们经验丰富的科学家团队随时乐意为您服务。

让我们为您提供帮助

属性

form

liquid

reaction suitability

reaction type: C-H Activation, reagent type: catalyst, reagent type: oxidant

refractive index

n/D 1.444

density

1.361 g/mL

InChI

1S/C10H11IO4/c1-8(12)14-11(15-9(2)13)10-6-4-3-5-7-10/h3-7H,1-2H3

InChI key

ZBIKORITPGTTGI-UHFFFAOYSA-N

说明

Application

Stoichiometric oxidant in the TEMPO oxidation of nerol to neral. Oxidant employed in the rhodium-catalyzed aziridination of olefins with sulfamate esters.

Useful reagent for the synthesis of a wide variety of heterocyclic compounds.

Unactivated sp³ C-H bonds of both oxime and pyridine substrates undergo highly regio- and chemoselective Pd(II)-catalyzed oxygenation with PhI(OAc)₂ as a stoichiometric oxidant.

Used in the room temperature Pd-catalyzed 2-arylation of indoles

Other Notes

Rh₂(esp)₂: An Exceptionally Efficient and Selective Catalyst for C-H Amination

pictograms

GHS08,GHS07

signalword

Warning

hcodes

H315,H319,H336,H351

pcodes

P202 - P261 - P264 - P302 + P352 - P305 + P351 + P338 - P308 + P313

Hazard Classifications

Carc. 2 - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Central nervous system

存储类别

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

法规信息

新产品

此项目有

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

It looks like we've run into a problem, but you can still download Certificates of Analysis from our 文件 section.

如需帮助，请联系客户支持

已有该产品？

在文件库中查找您最近购买产品的文档。

访问文档库

Palladium-catalyzed oxygenation of unactivated sp3 C-H bonds.

Lopa V Desai et al.

Journal of the American Chemical Society, 126(31), 9542-9543 (2004-08-05)

This communication describes a new palladium-catalyzed method for the oxygenation of unactivated sp3 C-H bonds. A wide variety of alkane substrates containing readily available oxime and/or pyridine directing groups are oxidized with extremely high levels of chemo-, regio-, and in

Copper-catalyzed diacetoxylation of olefins using PhI(OAc)2 as oxidant.

Jayasree Seayad et al.

Organic letters, 12(7), 1412-1415 (2010-03-13)

Copper(I) or -(II) salts with weakly coordinating anions catalyze the diacetoxylation of olefins efficiently in the presence of PhI(OAc)(2) as the oxidant under mild conditions. The reaction is effective for aryl, aryl alkyl, as well as aliphatic terminal and internal

First synthesis of 3-aryl-4-unsubstituted-6-CF(3)-pyridin-2-ones via aryl migration reaction in the presence of PhI(OAc)(2)/NaOH.

Hai Yi et al.

Chemical communications (Cambridge, England), 46(37), 6941-6943 (2010-08-24)

3-Aryl-4-unsubstituted-6-CF(3)-pyridin-2-ones have been efficiently synthesized from readily available 4-aryl-3-carbamoyl-6-CF(3)-pyridin-2(1H)-ones by treatment with PhI(OAc)(2) in the presence of NaOH.

查看所有相关文献

全球贸易项目编号

货号	GTIN
902772-25ML	04061838695321