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Merck
CN

903698

1-Isopropyl-4-methyl-5-norbornene

别名:

1-Isopropyl-4-methylbicyclo[2.2.1]hept-2-en

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关于此项目

经验公式(希尔记法):
C11H18
化学文摘社编号:
分子量:
150.26
UNSPSC Code:
12352200
Form:
liquid
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form

liquid

reaction suitability

reaction type: C-H Activation, reagent type: catalyst

storage temp.

2-8°C

Application

1-Isopropyl-4-methyl-5-norbornene is a norbornene ligand developed in the lab of Guanbing Dong for us in norbornene/palladium catalysis. The catalytic system of 1-Isopropyl-4-methyl-5-norbornene, [PdCl(allyl)]2 (683396), and RuPhos (663131) can be used for the site-selective ortho functionalization of aryl iodides.1

存储类别

10 - Combustible liquids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

法规信息

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Jianchun Wang et al.
Nature chemistry, 10(8), 866-872 (2018-06-27)
Achieving site-selectivity in arene functionalization that is complementary to the site-selectivity from electrophilic aromatic substitution reactions has been a long-standing quest in organic synthesis. Palladium/norbornene cooperative catalysis potentially offers a unique approach to this problem, but its use has been

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