912719
(S)-BIDIME
≥97%, powder
别名:
(S)-3-(tert-butyl)-4-(2,6-dimethoxyphenyl)-2,3-dihydrobenzo[d][1,3]oxaphosphole
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关于此项目
经验公式（希尔记法）:
C19H23O3P
化学文摘社编号:
分子量:
330.36
MDL number:
UNSPSC Code:
12352200
NACRES:
NA.22
产品名称
(S)-BIDIME, ≥97%
InChI key
BWPDUHMFZCEKIP-UHFFFAOYSA-N
SMILES string
P1(COc2c1c(ccc2)c3c(cccc3OC)OC)C(C)(C)C
assay
≥97%
form
powder
optical purity
ee: ≥99% (HPLC)
reaction suitability
reagent type: ligand
functional group
phosphine
Quality Level
Application
(S)-BIDIME is a P-chiral monophosphorus ligand used for the transition metal-catalyzed asymmetric Suzuki-Miyaura and hydroboration reactions.
Legal Information
Sold in collaboration with Zejun Pharmaceuticals
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
法规信息
新产品
此项目有
Wenzhen Fu et al.
Angewandte Chemie (International ed. in English), 54(8), 2520-2524 (2015-01-20)
The first asymmetric nickel-catalyzed intramolecular reductive cyclization of alkynones is reported. A P-chiral monophosphine and triethylsilane were used as the ligand and the reducing reagent, respectively, to form a series of tertiary allylic alcohols bearing furan/pyran rings in excellent yields
Naifu Hu et al.
Angewandte Chemie (International ed. in English), 55(16), 5044-5048 (2016-03-19)
A highly enantioselective alkene aryloxyarylation led to the high-yielding formation of a series of 1,4-benzodioxanes, 1,4-benzooxazines, and chromans containing quaternary stereocenters with excellent enantioselectivity. The sterically bulky and conformationally well defined chiral monophosphorus ligand L4 or L5 was responsible for
Ruofei Cheng et al.
Journal of the American Chemical Society, 140(13), 4508-4511 (2018-03-27)
Carborane cage chirality is an outstanding issue of great interest as the icosahedral carboranes have wide applications in medicinal and materials chemistry. The synthesis of optically active carborane derivatives, whose chirality is associated with the substitution patterns on the polyhedron
Naifu Hu et al.
Journal of the American Chemical Society, 137(21), 6746-6749 (2015-05-06)
The rhodium-catalyzed asymmetric hydroboration of α-arylenamides with BI-DIME as the chiral ligand and (Bpin)2 as the reagent yields for the first time a series of α-amino tertiary boronic esters in good yields and excellent enantioselectivities (up to 99% ee).
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