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Merck
CN

935638

三(三甲基硅基)磷

greener alternative

≥99.0%, anhydrous, battery grade

别名:

磷酸三(三甲基硅基)酯

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线性分子式:
[(CH3)3SiO]3P(O)
化学文摘社编号:
分子量:
314.54
UNSPSC Code:
12352005
Beilstein/REAXYS Number:
1794624
MDL number:
NACRES:
MA.24
Assay:
≥99.0%
Grade:
battery grade
Form:
(colorless liquid)
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产品名称

三(三甲基硅基)磷, ≥99.0%, anhydrous, battery grade

InChI

1S/C9H27O4PSi3/c1-15(2,3)11-14(10,12-16(4,5)6)13-17(7,8)9/h1-9H3

SMILES string

C[Si](C)(C)OP(=O)(O[Si](C)(C)C)O[Si](C)(C)C

InChI key

QJMMCGKXBZVAEI-UHFFFAOYSA-N

grade

battery grade

description

Application: Battery manufacturing

assay

≥99.0%

form

(colorless liquid)

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

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impurities

 ppm H2O≤500
≤500 ppm H2O

refractive index

n20/D 1.409 (lit.)

bp

228-229 °C/720 mmHg (lit.)
228-229 °C

mp

3-4 °C (lit.)
3-4 °C

density

0.945 g/mL at 25 °C (lit.)

application(s)

battery manufacturing

greener alternative category

Quality Level

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Application

Tris(trimethylsilyl) borate has a wide range of applications in various industries, including battery manufacturing, where it is used as an electrolyte additive, particularly in high-voltage lithium-ion batteries. TMSB is a cathode-film-forming additive that forms a thin protective coating called a solid-electrolyte interface (SEI) on the surface of the cathode. Adding TMSB to the electrolyte formulation, even at low concentrations of 0.5 wt.%, noticeably improves capacity retention for NMC, LMO, and LMNO cathodes. TMSB also is shown to reduce the flammability of the electrolyte and improve the thermal stability of LiPF6-based electrolytes at elevated temperatures.TMSB also has catalytic properties, which make it useful in organic synthesis reactions and as a reagent in the manufacturing of pharmaceuticals and other chemicals.

General description

Tris(trimethylsilyl) borate (TMSB) is an electron-deficient organoborate compound. It is a colorless liquid that that is miscible with many organic solvents, including the linear and cyclic carbonates used in battery applications. Our battery grade TMSB is differentiated by its high purity and low trace water content to ensure consistent and reliable performance in batteries.
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Click here for more information.

pictograms

FlameExclamation mark

signalword

Danger

Hazard Classifications

Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

存储类别

3 - Flammable liquids

wgk

WGK 2

flash_point_f

55.4 °F - closed cup

flash_point_c

13 °C - closed cup

法规信息

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Tris(trimethylsilyl)borate as an electrolyte additive for improving interfacial stability of high voltage layered lithium-rich oxide cathode/carbonate-based electrolyte
Li J, et al.
Journal of Power Sources, 285, 360-366 (2015)
Effect of tris(trimethylsilyl)borate on the high voltage capacity retention of LiNi0.5Co0.2Mn0.3O2/graphite cells
Zuo X, et al
Journal of Power Sources, 229, 308-312 (2013)
Tris(trimethylsilyl) borate as an electrolyte additive to improve the cyclability of LiMn2O4 cathode for lithium-ion battery
Liu Y, et al.
Journal of Power Sources, 221, 90-96 (2013)
Importance of Reduction and Oxidation Stability of High Voltage Electrolytes and Additives
Delp Samuel A, et.al
Electrochimica Acta, 498-510, 209-209 (2016)

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