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Merck
CN

935638

Sigma-Aldrich

三(三甲基硅基)磷

greener alternative

≥99.0%, anhydrous, battery grade

别名:

磷酸三(三甲基硅基)酯

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About This Item

线性分子式:
[(CH3)3SiO]3P(O)
CAS Number:
分子量:
314.54
Beilstein:
1794624
MDL编号:
UNSPSC代码:
12352005

等级

battery grade

质量水平

描述

Application: Battery manufacturing

方案

≥99.0%

表单

(colorless liquid)

环保替代产品特性

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

杂质

 ppm H2O≤500
≤500 ppm H2O

折射率

n20/D 1.409 (lit.)

沸点

228-229 °C/720 mmHg (lit.)
228-229 °C

mp

3-4 °C (lit.)
3-4 °C

密度

0.945 g/mL at 25 °C (lit.)

应用

battery manufacturing

环保替代产品分类

SMILES字符串

C[Si](C)(C)OP(=O)(O[Si](C)(C)C)O[Si](C)(C)C

InChI

1S/C9H27O4PSi3/c1-15(2,3)11-14(10,12-16(4,5)6)13-17(7,8)9/h1-9H3

InChI key

QJMMCGKXBZVAEI-UHFFFAOYSA-N

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一般描述

Tris(trimethylsilyl) borate (TMSB) is an electron-deficient organoborate compound. It is a colorless liquid that that is miscible with many organic solvents, including the linear and cyclic carbonates used in battery applications. Our battery grade TMSB is differentiated by its high purity and low trace water content to ensure consistent and reliable performance in batteries.
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Click here for more information.

应用

Tris(trimethylsilyl) borate has a wide range of applications in various industries, including battery manufacturing, where it is used as an electrolyte additive, particularly in high-voltage lithium-ion batteries. TMSB is a cathode-film-forming additive that forms a thin protective coating called a solid-electrolyte interface (SEI) on the surface of the cathode. Adding TMSB to the electrolyte formulation, even at low concentrations of 0.5 wt.%, noticeably improves capacity retention for NMC, LMO, and LMNO cathodes. TMSB also is shown to reduce the flammability of the electrolyte and improve the thermal stability of LiPF6-based electrolytes at elevated temperatures.TMSB also has catalytic properties, which make it useful in organic synthesis reactions and as a reagent in the manufacturing of pharmaceuticals and other chemicals.

象形图

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警示用语:

Danger

危险分类

Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

储存分类代码

3 - Flammable liquids

WGK

WGK 2

闪点(°F)

55.4 °F - closed cup

闪点(°C)

13 °C - closed cup


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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