T25305
四苯基氯化砷(V) 水合物
97%
别名:
四苯氯化砷, 苯基氯化砷
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关于此项目
线性分子式:
(C6H5)4As(Cl) · xH2O
化学文摘社编号:
分子量:
418.79 (anhydrous basis)
Beilstein:
3580063
EC 号:
MDL编号:
UNSPSC代码:
12161600
PubChem化学物质编号:
NACRES:
NA.22
质量水平
方案
97%
反应适用性
core: arsenic
reagent type: catalyst
mp
258-260 °C (lit.)
SMILES字符串
O.[Cl-].c1ccc(cc1)[As+](c2ccccc2)(c3ccccc3)c4ccccc4
InChI
1S/C24H20As.ClH.H2O/c1-5-13-21(14-6-1)25(22-15-7-2-8-16-22,23-17-9-3-10-18-23)24-19-11-4-12-20-24;;/h1-20H;1H;1H2/q+1;;/p-1
InChI key
NGDWSDTZKCSLRK-UHFFFAOYSA-M
应用
阳离子交换剂。用于制备砷酰胺、肟和碳水化合物衍生物。
警示用语：
Danger
危险声明
危险分类
Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1
储存分类代码
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
K Yoshioka et al.
Experientia, 42(9), 1022-1023 (1986-09-15)
The effect of lipophilic cations such as triphenylmethylphosphonium, tetraphenylphosphonium and tetraphenylarsonium in addition to dibenzyldimethylammonium on thiamine transport in isolated rat hepatocytes was studied. Lipophilic cations at the concentration 10 microM almost completely inhibited thiamine uptake. Kinetic studies showed that
Jens Schamberger et al.
Biophysical journal, 82(6), 3081-3088 (2002-05-23)
The magnitude of the dipole potential of lipid membranes is often estimated from the difference in conductance between the hydrophobic ions, tetraphenylborate, and tetraphenylarsonium or tetraphenylphosphonium. The calculation is based on the tetraphenylarsonium-tetraphenylborate hypothesis that the magnitude of the hydration
D Wolff et al.
Biochimica et biophysica acta, 688(1), 138-144 (1982-05-21)
In order to elucidate the mechanism of action of organochlorine insecticides on the ion transport in biological membranes, we have studied the effect of DDT and its analog DDE on the structural parameters of phosphatidylethanolamine (PE) planar bilayers. DDT and
Journal of the American Chemical Society, 114, 5130-5130 (1992)
P Gros et al.
Biochemistry, 31(7), 1992-1998 (1992-02-25)
The possibility that simple lipophilic cations such as tetraphenylphosphonium (TPA+), triphenylmethylphosphonium (TPMP+), and diphenyldimethylphosphonium (DDP+) are substrates for the multidrug-resistance transport protein, P-glycoprotein, was tested. Hamster cells transfected with and overexpressing mouse mdr1 or mouse mdr3 exhibit high levels of
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