蒸汽密度
2.9 (vs air)
等级
purum
方案
≥95.0% (GC)
杂质
≤3% tetrahydropyran
折射率
n20/D 1.440 (lit.)
n20/D 1.441
沸点
86 °C (lit.)
mp
−70 °C (lit.)
密度
0.922 g/mL at 25 °C (lit.)
SMILES字符串
C1COC=CC1
InChI
1S/C5H8O/c1-2-4-6-5-3-1/h2,4H,1,3,5H2
InChI key
BUDQDWGNQVEFAC-UHFFFAOYSA-N
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其他说明
醇的基团保护试剂
警示用语:
Danger
危险分类
Aquatic Chronic 3 - Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - Skin Sens. 1B
补充剂危害
储存分类代码
3 - Flammable liquids
WGK
WGK 3
闪点(°F)
5.0 °F - closed cup
闪点(°C)
-15 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
T. Nishiguchi et al.
Journal of the Chemical Society. Chemical Communications, 1766-1766 (1990)
T.W. Green et al.
Protective Groups in Organic Synthesis null
Weijun Yao et al.
Organic letters, 12(10), 2422-2425 (2010-05-01)
A cinchona alkaloid-catalyzed domino Michael/hemiacetalization reaction of cyclic beta-oxo aldehydes and aromatic beta,gamma-unsaturated alpha-keto esters, resulting in the formation of spiro-dihydropyran architectures in good yield with high stereoselectivity (up to 97% ee), is presented.
Yangbin Liu et al.
The Journal of organic chemistry, 77(8), 4136-4142 (2012-03-22)
A simple chiral diamine catalyst (1a) was successfully applied in the asymmetric Michael reaction between cyclic dimedone and α,β-unsaturated ketones. Both acyclic enones with aryl or alkyl β-substituents and cyclic enones were tolerated well in the reaction. The desired adducts
Debendra K Mohapatra et al.
Organic letters, 13(4), 744-747 (2011-01-11)
Highly stereoselective total syntheses of polyrhacitide A and epi-cryptocaryolone have been achieved in 11 steps with high overall yield of 24% and 28%, respectively, following a recently developed strategy for the construction of trans-2,6-disubstituted-3,4-dihydropyrans. In this report, the versatility of
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