93403
三(三苯基膦)氯化铑(I)
purum, ≥97.0% (CH)
别名:
NSC 124140, RhCl (PPh 3 ) 3, Wilkinson 催化剂, 三(三苯膦基)氯化铑(I)
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关于此项目
线性分子式:
[(C6H5)3P]3RhCl
化学文摘社编号:
分子量:
925.22
EC Number:
238-744-5
UNSPSC Code:
12352300
PubChem Substance ID:
Beilstein/REAXYS Number:
4581440
MDL number:
grade
purum
assay
≥97.0% (CH)
mp
245-250 °C (dec.)
storage temp.
2-8°C
SMILES string
Cl[Rh].c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6.c7ccc(cc7)P(c8ccccc8)c9ccccc9
InChI
1S/3C18H15P.ClH.Rh/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;/h3*1-15H;1H;/q;;;;+1/p-1
InChI key
IXAYKDDZKIZSPV-UHFFFAOYSA-M
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Application
signalword
Warning
hcodes
Hazard Classifications
Aquatic Chronic 4 - Skin Sens. 1
存储类别
11 - Combustible Solids
wgk
WGK 3
ppe
Eyeshields, Gloves, type N95 (US)
法规信息
新产品
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P Andrew Evans et al.
Journal of the American Chemical Society, 124(30), 8782-8783 (2002-07-26)
Transition metal-catalyzed cycloaddition reactions represent powerful methods for the construction of complex polycyclic systems. We have developed a new intermolecular metal-catalyzed [4 + 2 + 2] cycloaddition of heteroatom-tethered enyne derivatives with 1,3-butadiene. This study demonstrates that excellent selectivity can
Johannes Kiefer et al.
Chemphyschem : a European journal of chemical physics and physical chemistry, 9(15), 2207-2213 (2008-09-16)
Homogeneous catalysis in room-temperature ionic liquids (ILs) constitutes a most interesting field of research with high potential in technical applications. As concerns the hydrogenation of unsaturated hydrocarbons, Wilkinson's compound RhCl(PPh(3))(3) represents a catalyst that provides high selectivity and activity. Herein
Effect of catalytic hydrogenation of cellular lipid and fatty acid on the susceptibility of tumor cells to humoral immune killing.
S I Schlager
Methods in enzymology, 73(Pt B), 191-199 (1981-01-01)
V P Shevchenko et al.
Bioorganicheskaia khimiia, 36(2), 283-288 (2010-06-10)
1,2-Tritium-labeled 3-(O-carboxypropyl)- and 3-(O-carbomethoxypropyl)-oximes of 6alpha-methyl-16alpha,17alpha-cyclohexanopregn-4-ene-3,20-diones were obtained by the homogeneous catalytic hydrogenation of 1,2-dehydroprecursors with gaseous tritium and the subsequent separation of the resulting mixtures by HPLC. The specific radioactivities of 50-55 Ci/mmol were prepared using tris-(triphenylphosphine)-rhodium chloride.
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| D135909-100G | 04061833559574 |
| D135909-25G | 04061833559581 |
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