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Merck
CN

516813

过氧化氢 溶液

greener alternative

50 wt. % in H2O, stabilized

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关于此项目

经验公式(希尔记法):
H2O2
化学文摘社编号:
分子量:
34.01
UNSPSC Code:
12352304
NACRES:
NA.21
PubChem Substance ID:
EC Number:
231-765-0
Beilstein/REAXYS Number:
3587191
MDL number:
Assay:
48-52% H2O2 basis (by KMnO4, titration)
Concentration:
50 wt. % in H2O
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agency

suitable for EPA 200.7

Quality Level

vapor pressure

23.3 mmHg ( 30 °C)

assay

48-52% H2O2 basis (by KMnO4, titration)

reaction suitability

reaction type: C-H Activation, reagent type: catalyst, reagent type: oxidant

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

concentration

50 wt. % in H2O

mp

−40 °C

solubility

water: soluble at 20 °C

density

1.197 g/mL at 20 °C

greener alternative category

storage temp.

2-8°C

SMILES string

OO

InChI

1S/H2O2/c1-2/h1-2H

InChI key

MHAJPDPJQMAIIY-UHFFFAOYSA-N

General description

该产物是50%过氧化氢水溶液。过氧化氢更常用作绿色氧化剂。它是其他氧化剂的更好替代品,因为它的活性氧含量高,副产物是水。
We are committed to bringing you Greener Alternative Products, which adhere to one or more of the 12 Principles of Green Chemistry. This product has been enhanced for catalysis. Click here for more information.

Application

过氧化氢溶液可作为氧化剂用于以下反应:
  • 在均相金属催化剂存在下的烯烃环氧化。
  • 在金属催化剂存在下的氧化卤化。
  • 在聚合物固定化催化剂存在下硫化物氧化成亚砜和砜。

Other Notes

含有专有的无机锡基稳定剂


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Danger

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Chronic 3 - Eye Dam. 1 - Ox. Liq. 2 - Skin Corr. 1B - STOT SE 3

target_organs

Respiratory system

存储类别

5.1B - Oxidizing hazardous materials

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

法规信息

危险化学品
易制爆化学品

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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相关内容

This page is intended to make it easier to find the consumables you need based on the analytical method you’re using. Methods included on this page come from the EPA, Standard Methods and ASTM.


Recent developments on the epoxidation of alkenes using hydrogen peroxide as an oxidant.
Grigoropoulou G, et al.
Green Chemistry, 5(1), 1-7 (2003)
Efficient and selective hydrogen peroxide-mediated oxidation of sulfides in batch and segmented and continuous flow using a peroxometalate-based polymer immobilised ionic liquid phase catalyst.
Doherty S, et al.
Green Chemistry, 17(3), 1559-1571 (2015)
Oxidative halogenation with ?green? oxidants: oxygen and hydrogen peroxide.
Podgorsek A, et al.
Angewandte Chemie (International Edition in English), 48(45), 8424-8450 (2009)



全球贸易项目编号

货号GTIN
516813-4L04061832534657
516813-500ML04061837634345