M6633
α-D-Mannose pentaacetate
别名:
1,2,3,4,6-Penta-O-acetyl-α-D-mannopyranose
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关于此项目
经验公式（希尔记法）:
C16H22O11
化学文摘社编号:
分子量:
390.34
NACRES:
NA.25
PubChem Substance ID:
UNSPSC Code:
12352201
MDL number:
InChI
1S/C16H22O11/c1-7(17)22-6-12-13(23-8(2)18)14(24-9(3)19)15(25-10(4)20)16(27-12)26-11(5)21/h12-16H,6H2,1-5H3
SMILES string
CC(=O)OCC1OC(OC(C)=O)C(OC(C)=O)C(OC(C)=O)C1OC(C)=O
InChI key
LPTITAGPBXDDGR-UHFFFAOYSA-N
biological source
plant (ivory nut palm)
assay
≥98% (TLC)
form
powder
optical activity
[α]25/D 55.0 to 55.8°, c = 2.2% (w/v) in chloroform
technique(s)
thin layer chromatography (TLC): suitable
solubility
chloroform: 100 mg/mL, clear, colorless
storage temp.
−20°C
Quality Level
Application
α-D-Mannose pentaacetate was used for glycosylation in a study that assessed novel synthetic inhibitors of selectin-mediated cell adhesion. It has also been used in a study to investigate stereospecific entry to spiroketal glycosides using alkylidenecarbene C−H insertion.
General description
Mannose is a monosaccharide.
Other Notes
To gain a comprehensive understanding of our extensive range of Monosaccharides for your research, we encourage you to visit our Carbohydrates Category page.
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
法规信息
涉药品监管产品
此项目有
Duncan J Wardrop et al.
Organic letters, 4(4), 489-492 (2002-02-15)
[reaction: see text] A novel method for the stereospecific preparation of [4.5]spiroketal glycosides utilizing the 1,5 C-H bond insertion of alkylidenecarbenes is described. Treatment of 2-oxopropyl beta-pyranosides A with lithium (trimethylsilyl)diazomethane in THF at -78 degrees C afforded 1,6-dioxaspiro[4,5]decenes B
T P Kogan et al.
Journal of medicinal chemistry, 41(7), 1099-1111 (1998-04-17)
Reports of a high-affinity ligand for E-selectin, sialyl di-Lewis(x) (sLe(x)Le(x), 1), motivated us to incorporate modifications to previously reported biphenyl-based inhibitors that would provide additional interactions with the protein. These compounds were assayed for the ability to inhibit the binding
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