Reactions of organolithiums with dialkyl oxalates. A flow microreactor approach to synthesis of functionalized α-keto esters.

Reactions of organolithiums with dialkyl oxalates. A flow microreactor approach to synthesis of functionalized α-keto esters.

Chemical communications (Cambridge, England) (2013-03-15)

Aiichiro Nagaki, Daisuke Ichinari, Jun-ichi Yoshida

摘要

Reactions of functionalized aryllithiums with dialkyl oxalates were achieved using a flow microreactor to obtain α-keto esters with high selectivity by virtue of fast 1 : 1 micromixing.

材料

货号

品牌

产品描述

B57702

Sigma-Aldrich

溴苯, ReagentPlus^®, 99%

16350

Sigma-Aldrich

溴苯, ≥99.5% (GC)