Merck
CN
  • Pd-modified Au on carbon as an effective and durable catalyst for the direct oxidation of HMF to 2,5-furandicarboxylic acid.

Pd-modified Au on carbon as an effective and durable catalyst for the direct oxidation of HMF to 2,5-furandicarboxylic acid.

ChemSusChem (2013-03-16)
Alberto Villa, Marco Schiavoni, Sebastiano Campisi, Gabriel M Veith, Laura Prati
PMID23495091
摘要

Mixed noblility: We show that the modification of a gold/carbon catalyst with platinum or palladium produces stable and recyclable catalysts for the selective oxidation of 5-hydroxymethylfurfural (HMF) to 2,5-furandicarboxylic acid (FDCA): the support and nanoparticle chemistry directly mediate the selective oxidation of terminal hydroxyl groups in bio-derived HMF. This finding is a significant advance over current conversion technology because of the technological importance of FDCA.

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