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  • Fabrication and characterization of a highly sensitive hydroquinone chemical sensor based on iron-doped ZnO nanorods.

Fabrication and characterization of a highly sensitive hydroquinone chemical sensor based on iron-doped ZnO nanorods.

Dalton transactions (Cambridge, England : 2003) (2015-11-26)
Ahmad Umar, Ali Al-Hajry, Rafiq Ahmad, S G Ansari, Mohammed Sultan Al-Assiri, Hamed Algarni
摘要

Herein, we report the development of a simple and highly sensitive hydroquinone (HQ) chemical sensor based on an electrochemically activated iron-doped (Fe-doped) zinc oxide nanorod (ZnO NR) modified screen-printed electrode (SPE). The Fe-doped ZnO NRs were prepared using a hydrothermal process and their morphological, crystal, compositional and optical properties were characterized in detail. The detailed characterizations showed that the NRs are densely grown, well-crystalline and possess a wurtzite hexagonal phase. The fabricated HQ electrochemical sensor exhibited high sensitivity of 18.60 μA mM(-1) cm(-2) and a very low experimental detection limit of 0.51 μM. Our results demonstrate that simply prepared doped ZnO nanomaterials are promising candidates to fabricate highly sensitive electrochemical sensors.

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氢氧化铵 溶液, ACS reagent, 28.0-30.0% NH3 basis
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氢氧化铵 溶液, 28% NH3 in H2O, ≥99.99% trace metals basis
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六亚甲基四胺, ACS reagent, ≥99.0%
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氢氧化铵 溶液, puriss., 30-33% NH3 in H2O
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对苯二酚, ReagentPlus®, ≥99%
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对苯二酚, ReagentPlus®, 99%
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六亚甲基四胺, ReagentPlus®, 99%
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氢氧化铵 溶液, puriss. p.a., reag. ISO, reag. Ph. Eur., ~25% NH3 basis
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六亚甲基四胺, puriss. p.a., reag. Ph. Eur., ≥99.5% (calc. to the dried substance)
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氢氧化铵 溶液, puriss. p.a. plus, ≥25% NH3 in H2O
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氢氧化铵 溶液, puriss., meets analytical specification of Ph. Eur., 25-30% NH3 basis
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对苯二酚, meets USP testing specifications
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六亚甲基四胺, meets analytical specification of Ph. Eur., BP, 99-100.5% (calc. to the dried substance)