399191
三氟乙酸铑(II)二聚体
别名:
三氟乙酸铑(II)盐二聚体
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关于此项目
线性分子式:
[(CF3COO)2Rh]2
CAS Number:
分子量:
657.87
MDL编号:
UNSPSC代码:
12352103
PubChem化学物质编号:
NACRES:
NA.23
质量水平
表单
powder
反应适用性
reagent type: catalyst
SMILES字符串
FC(F)(F)C(=O)O[Rh]OC(=O)C(F)(F)F.FC(F)(F)C(=O)O[Rh]OC(=O)C(F)(F)F
InChI
1S/4C2HF3O2.2Rh/c4*3-2(4,5)1(6)7;;/h4*(H,6,7);;/q;;;;2*+2/p-4
InChI key
PQEXTYUESSEHKW-UHFFFAOYSA-J
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应用
用于制备异构体纯的 α,β-不饱和羰基化合物以及一、二、三维分子固体的结构单元。
其他说明
含有痕量乙酸铑
警示用语：
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
Li-Feng Mao et al.
Inorganic chemistry, 35(11), 3183-3187 (1996-05-22)
The complexes trans-[MI(2)(CNC(6)H(4)-CN-4)(2)], (M = Pd and Pt), trans-[FeI(2)L(4)] (L = CNC(6)H(4)-CN-4 and CNC(6)H(2)-Me(2)-2,6-CN-4), and [Mn(CNC(6)H(4)-CN-4)(6)][SO(3)CF(3)] were prepared. The compounds are thermally stable up to 230 degrees C or higher. The molecular structure of trans-[FeI(2)(CNC(6)H(4)-CN-4)(4)] was determined by X-ray crystallography:
A Convenient Method for the Preparation of (Z)-alpha,beta-Unsaturated Carbonyl Compounds.
Douglass F. Taber et al.
The Journal of organic chemistry, 61(8), 2908-2910 (1996-04-19)
Ligand-induced fate of embryonic species in the shape-controlled synthesis of rhodium nanoparticles.
Adam J Biacchi et al.
ACS nano, 9(2), 1707-1720 (2015-01-30)
The shapes of noble metal nanoparticles directly impact their properties and applications, including in catalysis and plasmonics, and it is therefore important to understand how multiple distinct morphologies can be controllably synthesized. Solution routes offer powerful capabilities for shape-controlled nanoparticle
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