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经验公式(希尔记法):
C16H26O2Rh2
化学文摘社编号:
分子量:
456.19
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
MDL number:
产品名称
羟基(环辛二烯)铑(I) 二聚体, 95%
SMILES string
O[Rh].O[Rh].C1CC=CCCC=C1.C2CC=CCCC=C2
InChI
1S/2C8H12.2H2O.2Rh/c2*1-2-4-6-8-7-5-3-1;;;;/h2*1-2,7-8H,3-6H2;2*1H2;;/q;;;;2*+1/p-2/b2*2-1-,8-7-;;;;
InChI key
IUAQXTGDGDIMOD-MIXQCLKLSA-L
assay
95%
form
solid
reaction suitability
core: rhodium, reagent type: catalyst
greener alternative product characteristics
Catalysis
Learn more about the Principles of Green Chemistry.
sustainability
Greener Alternative Product
mp
199 °C (dec.)
greener alternative category
Quality Level
General description
我们致力于为您提供更环保的替代产品,以符合“绿色化学的12项原则”的一项或多项原则要求。该产品为增强型,提高了催化效率。点击此处以获取更多信息。
Application
在铑催化剂作用下,R-BINAP 或 R-SEGPHOS® 配体可合成手性 3,3-二取代-1-茚满酮。
Legal Information
SEGPHOS is a registered trademark of Takasago Intl. Corp.
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
Rhodium-catalyzed asymmetric synthesis of 3,3-disubstituted 1-indanones.
Ryo Shintani et al.
Angewandte Chemie (International ed. in English), 46(20), 3735-3737 (2007-04-05)
商品
Discover the role of boronic acids in enantioenriched C(sp2)–C(sp2) product synthesis, specifically the rhodium-catalyzed Suzuki–Miyaura-type arylations of allylic halides and cyclobutenes.
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