662623
双[(α,α,α′,α′-四甲基-1,3-苯二丙酸)铑]
95%, solid
别名:
Rh2(esp)2
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关于此项目
经验公式（希尔记法）:
C32H40O8Rh2
化学文摘社编号:
分子量:
758.47
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
MDL number:
产品名称
双[(α,α,α′,α′-四甲基-1,3-苯二丙酸)铑], 95%
SMILES string
[Rh][Rh].CC(C)(Cc1cccc(CC(C)(C)C(O)=O)c1)C(O)=O.CC(C)(Cc2cccc(CC(C)(C)C(O)=O)c2)C(O)=O
InChI key
OBMUTUNJWNQIAJ-UHFFFAOYSA-N
InChI
1S/2C16H22O4.2Rh/c2*1-15(2,13(17)18)9-11-6-5-7-12(8-11)10-16(3,4)14(19)20;;/h2*5-8H,9-10H2,1-4H3,(H,17,18)(H,19,20);;
assay
95%
form
solid
reaction suitability
core: rhodium
reagent type: catalyst
reaction type: C-H Activation
mp
>300 °C
Quality Level
Application
双[α,α,α′,α′-四甲基-1,3-苯二丙酸铑] 可作为催化剂用于脲和胍衍生的底物的 C−H 氧化胺化以生成相应的杂环产物。
General description
双[α,α,α′,α′-四甲基-1,3-苯二丙酸铑] 已被确认为高效的C-H 活化催化剂。
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
Kristin Williams Fiori et al.
Journal of the American Chemical Society, 129(3), 562-568 (2007-01-18)
Reaction methodology for intermolecular C-H amination of benzylic and 3 degrees C-H bonds is described. This process uses the starting alkane as the limiting reagent, gives optically pure tetrasubstituted amines through stereospecific insertion into enantiomeric 3 degrees centers, displays high
商品
New! Rh2(esp)2, and exceptionally efficient and selective catalyst for C-H amination.
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