795674
3-(Trimethylsilyl)pyridin-2-yl trifluoromethanesulfonate
95%
别名:
Garg 2,3-pyridyne precursor
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关于此项目
经验公式（希尔记法）:
C9H12F3NO3SSi
化学文摘社编号:
分子量:
299.34
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
MDL number:
Assay:
95%
Form:
liquid
Quality Level
assay
95%
form
liquid
refractive index
n/D 1.454
density
1.266 at 25 °C
functional group
fluoro, triflate
storage temp.
2-8°C
SMILES string
[Si](C)(C)(C)c1c(nccc1)O[S](=O)(=O)C(F)(F)F
InChI
1S/C9H12F3NO3SSi/c1-18(2,3)7-5-4-6-13-8(7)16-17(14,15)9(10,11)12/h4-6H,1-3H3
InChI key
SXIBFUWSBRRXRJ-UHFFFAOYSA-N
Application
Pyridyne precursor can be activated under mild fluoride conditions; which are highly reactive with dienes and other dipolariphiles (e.g. azides) to provide cycloaddition products containing an indole motif.
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
法规信息
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New and efficient methods for the synthesis of functionalized heterocycles are highly sought after.
相关内容
The Garg group develops methods for the synthesis of natural products and pharmaceuticals. One key method pertains to heterocyclic arynes, such as indolynes and pyridynes, which are generated in situ from silyltriflate precursors under mild fluoride based reaction conditions.
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 795674-100MG | 04061833243046 |
| 795674-1G | 04061826655290 |