产品名称
AlPhos Pd G6 Br,
SMILES string
[Pd](Br)c%10ccc(cc%10)C(F)(F)F.Fc1c(c(c(c(c1CCCC)F)F)c2c(c(c(cc2C(C)C)C(C)C)c3c(c(ccc3)OC)P([C@]87C[C@H]9C[C@@H](C8)C[C@@H](C7)C9)[C@]54C[C@H]6C[C@@H](C5)C[C@@H](C4)C6)C(C)C)F
InChI key
JVLLMZKJAGOHTQ-HZBKTHAQSA-M
form
powder
reaction suitability
reagent type: catalyst
reaction type: Cross Couplings
Quality Level
Application
AlPhos Pd G6 Br is a G6 Buchwald precatalyst. The G6 precatalysts are air-stable, palladium-based oxidative addition complexes (OACs) that offer an alternative to the previously developed classes of palladacycle precatalysts. Unlike previous generations, the bulkiest biarylphosphine ligand precatalysts are readily prepared. These precatalysts have been shown to be effective for many reactions, including C-N, C-O, and C-F cross couplings.
Learn more about G6 Buchwald precatalysts
Learn more about G6 Buchwald precatalysts
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Bryan T Ingoglia et al.
Organic letters, 19(11), 2853-2856 (2017-05-13)
In this report, we describe the application of palladium-based oxidative addition complexes (OACs) as effective precatalysts for C-N, C-O, and C-F cross-coupling reactions with a variety of (hetero)arenes. These complexes offer a convenient alternative to previously developed classes of precatalysts
商品
Buchwald G6 precatalysts are oxidative addition complexes that are thermally, air, and moisture stable. The catalyst activation doesn’t require a base and generates innocuous byproducts.
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