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Merck
CN

915602

Sigma-Aldrich

AlPhos Pd G6 Br

powder

别名:

AlPhos OAC precatalyst Br

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关于此项目

经验公式(希尔记法):
C59H71BrF7OPPd
化学文摘社编号:
分子量:
1146.48
UNSPSC代码:
12352300
NACRES:
NA.22
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产品名称

AlPhos Pd G6 Br,

表单

powder

质量水平

反应适用性

reagent type: catalyst
reaction type: Cross Couplings

SMILES字符串

[Pd](Br)c%10ccc(cc%10)C(F)(F)F.Fc1c(c(c(c(c1CCCC)F)F)c2c(c(c(cc2C(C)C)C(C)C)c3c(c(ccc3)OC)P([C@]87C[C@H]9C[C@@H](C8)C[C@@H](C7)C9)[C@]54C[C@H]6C[C@@H](C5)C[C@@H](C4)C6)C(C)C)F

InChI key

JVLLMZKJAGOHTQ-HZBKTHAQSA-M

相关类别

应用

AlPhos Pd G6 Br is a G6 Buchwald precatalyst. The G6 precatalysts are air-stable, palladium-based oxidative addition complexes (OACs) that offer an alternative to the previously developed classes of palladacycle precatalysts. Unlike previous generations, the bulkiest biarylphosphine ligand precatalysts are readily prepared. These precatalysts have been shown to be effective for many reactions, including C-N, C-O, and C-F cross couplings.

Learn more about G6 Buchwald precatalysts

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Bryan T Ingoglia et al.
Organic letters, 19(11), 2853-2856 (2017-05-13)
In this report, we describe the application of palladium-based oxidative addition complexes (OACs) as effective precatalysts for C-N, C-O, and C-F cross-coupling reactions with a variety of (hetero)arenes. These complexes offer a convenient alternative to previously developed classes of precatalysts

商品

Buchwald G6 precatalysts are oxidative addition complexes that are thermally, air, and moisture stable. The catalyst activation doesn’t require a base and generates innocuous byproducts.

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