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Zheng Liu et al.
Nature communications, 2, 305-305 (2011-05-11)
The conductance of single-molecule junctions may be governed by the structure of the molecule in the gap or by the way it bonds with the leads, and the information contained in a Raman spectrum is ideal for examining both. Here
Coordination Polymers of Co(NCS)2 with Pyrazine and 4,4`-Bipyridine:? Syntheses and Structures
Lu J, et al.
Inorganic Chemistry, 36 (5), 923- 929 null
Stephen D Burd et al.
Journal of the American Chemical Society, 134(8), 3663-3666 (2012-02-10)
A previously known class of porous coordination polymer (PCP) of formula [Cu(bpy-n)(2)(SiF(6))] (bpy-1 = 4,4'-bipyridine; bpy-2 = 1,2-bis(4-pyridyl)ethene) has been studied to assess its selectivity toward CO(2), CH(4), N(2), and H(2)O. Gas sorption measurements reveal that [Cu(bpy-1)(2)(SiF(6))] exhibits the highest
Victor Mamane et al.
The Journal of organic chemistry, 77(6), 2579-2583 (2012-03-01)
A chiral polyhalogenated 4,4'-bipyridine derivative is described allowing an easy access to a new family of chiral 4,4'-bipyridines by site-selective cross-coupling reactions. The absolute configurations of all the HPLC separated enantiomers were determined by X-ray diffraction and electronic circular dichroism
Amy R Mulholland et al.
Organic & biomolecular chemistry, 10(30), 6045-6053 (2012-05-15)
Synthetic access to a set of metallo- and free base bis-porphyrins has been provided by a stepwise approach involving sequential peptide and Suzuki couplings. Linking these porphyrins through a 3,3'-biphenyl bridge enables cooperative binding to ditopic ligands such as the
Bottom-up approach for the preparation of hybrid nanosheets based on coordination polymers made of metal-diethyloxaloacetate complexes linked by 4, 4′-bipyridine.
Portoles-Gil N, et al.
CrystEngComm, 19(34), 4972-4982 (2017)
Masaru Yao et al.
Scientific reports, 5, 10962-10962 (2015-06-05)
Is it possible to exceed the lithium redox potential in electrochemical systems? It seems impossible to exceed the lithium potential because the redox potential of the elemental lithium is the lowest among all the elements, which contributes to the high
Xuefeng Zhu et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 17(12), 3429-3437 (2011-02-23)
A series of amphiphilic L-glutamic acid derivatives with various saturated alkyl chains has been designed and their co-assembly with 4,4'-bipyridine in aqueous media has been investigated. While the individual amphiphiles formed hydrogels with water and self-assembled into fine fiber networks
Tamas Panda et al.
Chemical communications (Cambridge, England), 47(27), 7674-7676 (2011-06-11)
Three new metal-organic framework isomers have been synthesized by using the organic linker 5-triazole isophthalic acid and Mn(NO(3))(2)·xH(2)O. Structural conversions from non-porous to porous MOFs due to the template effect have been observed. The cross-sectional pore apertures of the resulting
Chong-Zhen Mei et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 81(1), 764-768 (2011-07-29)
A new 3D metal-organic coordination polymer [Cd(H(3)BPTC)(2)(bpy)](n) (1) (H(4)BPTC = 1,1'-biphenyl-2,2',6,6'-tetracarboxylic acid, bpy =4,4'-bipyridine) has been synthesized and characterized by single X-ray diffraction and IR spectroscopy. The one-dimensional metal-organic chains of the title complex, namely [Cd(H(3)BPTC)(2)](n), are held together through
Yingwei Zhang et al.
PloS one, 7(1), e30426-e30426 (2012-01-27)
In this paper, we report on the large-scale, rapid synthesis of uniform rectangular coordination polymer nanoplates (RCPNs) assembled from Cu(II) and 4,4'-bipyridine for the first time. We further demonstrate that such RCPNs can be used as a very effective fluorescent
Crystal engineering of coordination polymers using 4, 4′-bipyridine as a bond between transition metal atoms.
Biradha K, et al.
Chemical Communications (Cambridge, England), 138(40), 4169-4179 (2006)
Ultrafast photoinduced interfacial proton coupled electron transfer from cdse quantum dots to 4, 4′-bipyridine.
Chen J, et al.
Journal of the American Chemical Society, 138(3), 884-892 (2016)
Chao-Yan Zhang et al.
Journal of chromatography. A, 1383, 18-24 (2015-01-27)
Three Ag(I)-organic frameworks, [Ag5(pydc)2(CN)]n, {[Ag4(pydc)2]CH3CN}n, and [Ag(4,4'-bpy)NO3]n, were synthesized and embedded into silica gels to form metal-organic-framework (MOF)-embedded gels for the microextraction of polybrominated diphenyl ethers (PBDEs) in soils. Despite the great differences in the structures of the organic ligands
Kumar Biradha et al.
Chemical communications (Cambridge, England), (40)(40), 4169-4179 (2006-10-13)
Coordination polymers have attracted an enormous interest among chemists due to their novel physical and chemical properties. This review describes the role of 4,4'-bipyridine in discovering various coordination polymers with novel topologies that range from one-dimensional to three dimensional. The
Lei Li et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 86, 56-61 (2011-11-05)
Three titanium coordination polymers, {[Ti(SO(4))(2)(H(2)O)]·0.5bipy·2H(2)O}(n)1, {[Ti1(SO(4))(2)(H(2)O)]·[Ti2(SO(4))(2)(H(2)O)]·bipy·5H(2)O}(n)2 and [Ti(tea)](n)3 (bipy=4,4'-bipyridine, H(3)tea=triethanolamine) were synthesized and characterized by IR, UV-Vis absorption spectra, TG analysis, X-ray single crystal diffraction and surface photovoltage spectroscopy (SPS). The surface photoelectric properties of titanium coordination polymers were discussed
Homan Kang et al.
Scientific reports, 5, 10144-10144 (2015-05-29)
Recently, preparation and screening of compound libraries remain one of the most challenging tasks in drug discovery, biomarker detection, and biomolecular profiling processes. So far, several distinct encoding/decoding methods such as chemical encoding, graphical encoding, and optical encoding have been
Guichi Zhu et al.
Analytica chimica acta, 697(1-2), 61-66 (2011-06-07)
In this report, we present a novel approach to detect clenbuterol based on competitive surface-enhanced Raman scattering (SERS) immunoassay. Herein, a SERS nanoprobe that relies on gold nanoparticle (GNP) is labeled by 4,4'-dipyridyl (DP) and clenbuterol antibody, respectively. The detection
Yuh Hijikata et al.
Chemical communications (Cambridge, England), 47(27), 7632-7634 (2011-06-11)
We have demonstrated downsizing effects of the soft porous crystal, [Zn(isophthalate)(4,4'-bipyridyl)](n) (CID-1), on the adsorption behavior between CID-1 and CID-1 nanocrystal (NCID-1). The difference results from the packing crystal structures and the dynamics of the frameworks.
Quirina Ferreira et al.
Nanotechnology, 22(43), 435604-435604 (2011-10-06)
Molecular-scale devices can be made using a step-by-step procedure, in a controllable and highly versatile way. In this report, we describe the growth of molecular wires (MW) from zinc (II) octaethylporphyrin (ZnOEP) assembled on highly oriented pyrolytic graphite (HOPG) by
Melissa C Grenier et al.
Bioorganic & medicinal chemistry letters, 22(12), 4055-4058 (2012-05-15)
Dialkyl 4,4'-bipyridinium compounds are widely employed for their useful redox properties, and are commonly known as viologens due to their intense coloration upon reduction. Despite their prevalence and amphiphilic nature, the antibacterial activity of these compounds remains largely unreported. We
Paola Peluso et al.
Journal of chromatography. A, 1251, 91-100 (2012-07-10)
The high performance liquid chromatography (HPLC) enantioseparation of eleven atropisomeric 4,4'-bipyridines was performed in the normal and polar organic phase mode using three cellulose-based chiral stationary phases (CSPs), namely Lux Cellulose-1, Lux Cellulose-2, Lux Cellulose-4, and two amylose-based CSPs, Chiralpak
Elena López-Torres et al.
Journal of inorganic biochemistry, 105(5), 600-608 (2011-03-30)
Several methyltin(IV) and butyltin(IV) complexes with the ligand benzil bis(benzoylhydrazone) and 4,4'-bipyridyl as coligand were synthesised and characterized by elemental analysis and by IR, (1)H, (13)C and (119)Sn NMR spectroscopies. Some of them were also analyzed using single crystal X-ray
Yamina Akacem et al.
The journal of physical chemistry. A, 116(4), 1261-1271 (2012-01-10)
The aluminum distribution effects on the adsorption of 4,4'-bipyridine (44BPY) in the straight channel of H-ZSM-5 simulated by two ten-membered ring clusters (2-10T) have been investigated by DFT methods. The energetic and structural properties of the complexes formed upon interaction
Investigation of supramolecular interaction in 4, 4′-bipyridine crystal by hydrostatic pressure spectroscopies.
Li A, et al.
Spectrochimica Acta. Part A, Molecular and Biomolecular Spectroscopy, 202(40), 70-75 (2018)
Luca Rigamonti et al.
Dalton transactions (Cambridge, England : 2003), 40(13), 3381-3393 (2011-02-23)
The synthesis and the characterization of new dinuclear copper(II) compounds of general formula [(L(a-d))(2)Cu(2)(μ-N-N)](ClO(4))(2) (1-6) with either neutral aliphatic diamine (N-N = piperazine, pip) or aromatic diimine (N-N = 4,4'-bipyridine, 4,4'-bipy) linker are reported. The copper ligands L(-) (L(a-) =
Christophe Kahlfuss et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 24(49), 13009-13019 (2018-07-28)
We have developed a strategy enabling control over the organization of ditopic molecular tectons within a palladium-based self-assembled system. The key electron-responsive sub-unit is a viologen-based mechanical hinge that can toggle under electric stimulation between a folded and a stretched
Tatsuya Konishi et al.
Journal of the American Chemical Society, 135(3), 1009-1014 (2012-10-18)
The in situ observation of geometrical and electronic structural dynamics of a single molecule junction is critically important in order to further progress in molecular electronics. Observations of single molecular junctions are difficult, however, because of sensitivity limits. Here, we
Mausam Kalita et al.
Inorganic chemistry, 51(8), 4521-4526 (2012-03-27)
We report a new class of derivatized 4,4'-bipyridinium ligands for use in synthesizing highly fluorescent, extremely stable, water-soluble CdSe and CdTe quantum dots (QDs) for bioconjugation. We employed an evaporation-condensation technique, also known as solvated metal atom dispersion (SMAD), followed
Meng-Yao Chao et al.
Dalton transactions (Cambridge, England : 2003), 47(38), 13722-13729 (2018-09-15)
The two-dimensional (2D) metal-organic framework (MOF) [Cd2.25Co0.75(BTB)2(DEF)4]·2(DEF)0.5 (1a, BTB = benzene-1,3,5-tribenzolate; DEF = N,N'-diethylformamide) featuring linear trimetallic cluster secondary building units (SBUs) and replaceable DEF solvates reacts smoothly with dipyridyl ligands DPS, DPDS, and BIPY (DPS = 4,4'-dipyridyl sulfide; DPDS
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