Construction of Grape-like Silica-Based Hierarchical Porous Interlocked Microcapsules by Colloidal Crystals Templates.

We present a facile strategy to prepare grape-like silica-based hierarchical porous interlocked microcapsules (HPIMs) by polystyrene colloidal crystals templates, whose structure is the subtle integration of open mouthed structure, hierarchical porous nanostructure and interlocked architecture. HPIMs are fabricated by replicating colloidal crystals templates that have a hexagonal close-packed structure; thus, theoretically, each microcapsule has 12 open mouths, and these open mouths with mesoporous microcapsule wall construct the hierarchical porous structure. Furthermore, the interlocked architecture of the microcapsules can endow HPIMs with excellent mechanical stability and recyclability. By adjusting sulfonation time, the morphology, shell thickness, and even mesporous size of the HPIMs can be precisely controlled. In addition, HPIMs with various compositions are obtained via this method, such as silica and aminopropyl polysilsesquioxane (APSQ). All these unique features derived from a readily available method will give products with a broader range of applications.