trans-Bis(tricyclohexylphosphine)(2-methylphenyl)nickel(II) chloride

Name: <I>trans</I>-Bis(tricyclohexylphosphine)(2-methylphenyl)nickel(II) chloride
Brand: ALDRICH

≥95%

别名:

trans-(PCy₃)₂Ni(o-tolyl)Cl

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经验公式（希尔记法）:

C₄₃H₇₃ClNiP₂

化学文摘社编号:

123839-28-1

分子量:

746.13

UNSPSC Code:

12352200

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产品名称

trans-Bis(tricyclohexylphosphine)(2-methylphenyl)nickel(II) chloride, ≥95%

SMILES string

Cl[Ni](C1=C(C)C=CC=C1)(P(C2CCCCC2)(C3CCCCC3)C4CCCCC4)P(C5CCCCC5)(C6CCCCC6)C7CCCCC7

assay

≥95%

form

powder or solid

reaction suitability

core: nickel
reaction type: Cross Couplings
reagent type: catalyst

mp

>300 °C

Application

The following Ni-complex is an air-stable precatalyst for various Ni-catalyzed reactions which normally require Ni(cod)₂, however, this precatalyst will not require any glovebox or schlenk techniques that must be followed with Ni(cod)₂. Rates are enhanced and selectivity is maintained when compared to the same reaction with Ni(cod)₂.

Legal Information

Patent application PCT/US2014/064565. Sold under license from the Massachusetts Institute of Technology.

Other Notes

存储类别

4.1B - Flammable solid hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

法规信息

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

MKCF3679

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Recent advances in homogeneous nickel catalysis.

Tasker S Z, et al.

Nature, 509(7500), 299-299 (2014)

Recent advances in homogeneous nickel catalysis.

Sarah Z Tasker et al.

Nature, 509(7500), 299-309 (2014-05-16)

Tremendous advances have been made in nickel catalysis over the past decade. Several key properties of nickel, such as facile oxidative addition and ready access to multiple oxidation states, have allowed the development of a broad range of innovative reactions.

商品

Jamison Nickel (II) Precatalysts

The Jamison group has developed a library of bench-stable phosphine-containing nickel(II) precatalysts that are converted into active catalysts in situ.

Nickel-based Catalysts

Nickel complexes catalyze various synthetic reactions like oxidative addition, C-H activation, and cross-coupling.

trans-Bis(tricyclohexylphosphine)(2-methylphenyl)nickel(II) chloride

≥95%

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关于此项目

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属性

产品名称

SMILES string

assay

form

reaction suitability

mp

说明

Application

Legal Information

Other Notes

安全信息

存储类别

wgk

flash_point_f

flash_point_c

法规信息

文件

分析证书(COA)

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