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901169

trans-Bis(methyldiphenylphosphine)(2-methylphenyl)nickel(II) chloride

Name: <I>trans</I>-Bis(methyldiphenylphosphine)(2-methylphenyl)nickel(II) chloride
Brand: ALDRICH

别名:

trans-(PPh₂Me)₂Ni(o-tolyl)Cl

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关于此项目

经验公式（希尔记法）:

C₃₃H₃₃ClNiP₂

化学文摘社编号:

1594112-89-6

分子量:

585.71

UNSPSC Code:

12352200

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属性

form

powder or solid

reaction suitability

core: nickel, reaction type: Cross Couplings, reagent type: catalyst

mp

152-157 °C

SMILES string

Cl[Ni](PC([H])([H])[H])(P(C1=C([H])C([H])=C([H])C([H])=C1[H])(C2=C([H])C([H])=C([H])C([H])=C2[H])C([H])([H])[H])C3=C(C([H])([H])[H])C([H])=C([H])C([H])=C3[H].[H]C4=C(C5=C([H])C([H])=C([H])C([H])=C5[H])C([H])=C([H])C([H])=C4[H]

说明

Application

The following Ni-complex is an air-stable precatalyst for various Ni-catalyzed reactions which normally require Ni(cod)₂, however, this precatalyst will not require any glovebox or schlenk techniques that must be followed with Ni(cod)₂. Rates are enhanced and selectivity is maintained when compared to the same reaction with Ni(cod)₂.

Other Notes

Legal Information

Patent application PCT/US2014/064565. Sold under license from the Massachusetts Institute of Technology.

存储类别

4.1B - Flammable solid hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

法规信息

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

MKCN4779

MKCF3678

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商品

Jamison Nickel (II) Precatalysts

The Jamison group has developed a library of bench-stable phosphine-containing nickel(II) precatalysts that are converted into active catalysts in situ.

Nickel-based Catalysts

Nickel complexes catalyze various synthetic reactions like oxidative addition, C-H activation, and cross-coupling.

全球贸易项目编号

货号	GTIN
901169-100MG	04061833259573